Shudo Hiroki, Kuwayama Motonobu, Segawa Yasutomo, Yagi Akiko, Itami Kenichiro
Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan.
JST-ERATO, Itami Molecular Nanocarbon Project, Nagoya University, Chikusa, Nagoya 464-8602, Japan.
Chem Commun (Camb). 2023 Nov 9;59(90):13494-13497. doi: 10.1039/d3cc04887j.
Fluorinated cycloparaphenylenes (FCPPs) have attracted attention as electron-accepting CPPs as well as strained fluoroarenes. Herein, we report the synthesis and properties of novel FCPPs; F[8]CPP and F[6]CPP. Furthermore, the derivatization of F[8]CPP afforded a new carbon nanoring where sixteen pyrrole rings are densely substituted on the CPP framework.
氟化环对亚苯基（FCPPs）作为电子接受型环对亚苯基以及具有张力的氟代芳烃已引起关注。在此，我们报道了新型FCPPs；F[8]CPP和F[6]CPP的合成及性质。此外，F[8]CPP的衍生化得到了一种新的碳纳米环，其中十六个吡咯环密集地取代在环对亚苯基骨架上。
