Chen Ju, Liu Xianghui, Wang Pan, Xiao Chengyu, Chen Shaowen, Zhou Han
State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai, 200240, People's Republic of China.
Shenzhen Research Institute, Shanghai Jiao Tong University, Shenzhen, 518057, People's Republic of China.
Nanotechnology. 2023 Nov 16;35(5). doi: 10.1088/1361-6528/ad074f.
Selective mid-infrared (MIR) radiation is highly desirable in many applications. However, there are still great challenges to simultaneously achieve MIR camouflage and radiative cooling utilizing simple structure. This work theoretically and experimentally proposes a bi-layer metamaterial composed of aluminum doped zinc oxide (AZO) nanoparticles embedded in AlOmatrix on the aluminum film. The bi-layer metamaterial exhibits high performance in MIR camouflage with radiative cooling, a low emissivity (ε3-5μm= 0.11,ε8-14μm= 0.20) in atmospheric windows and a high emissivity (ε5-8μm= 0.81) in non-atmospheric windows. The interaction of the epsilon-near-zero (ENZ) mode and localized surface plasmon resonance (LSPR) mode is responsible for the perfect emission over the wavelength range of 5-8μm. Additionally, the proposed selective MIR emitter supports large-angle incidence and has great polarization insensitivity. This demonstrates that epsilon-near-zero material-based bi-layer metamaterial is highly promising for the development of selective mid-infrared radiation.
在许多应用中,选择性中红外(MIR)辐射非常受欢迎。然而,利用简单结构同时实现MIR伪装和辐射冷却仍然面临巨大挑战。这项工作从理论和实验上提出了一种双层超材料,它由嵌入铝膜上AlO基质中的铝掺杂氧化锌(AZO)纳米颗粒组成。这种双层超材料在具有辐射冷却功能的MIR伪装方面表现出高性能、在大气窗口具有低发射率(ε3 - 5μm = 0.11,ε8 - 14μm = 0.20)以及在非大气窗口具有高发射率(ε5 - 8μm = 0.81)。近零介电常数(ENZ)模式与局域表面等离子体共振(LSPR)模式的相互作用导致了在5 - 8μm波长范围内的完美发射。此外,所提出的选择性MIR发射器支持大角度入射并且具有很大的偏振不敏感性。这表明基于近零介电常数材料的双层超材料在选择性中红外辐射的发展方面极具前景。