Lv Chun, He Pengyi, Pang Guowei, Liu Jie
College of Architecture and Civil Engineering, Qiqihar University, Qiqihar 161006, China.
College of Light-Industry and Textile Engineering, Qiqihar University, Qiqihar 161006, China.
Molecules. 2023 Oct 20;28(20):7189. doi: 10.3390/molecules28207189.
To study the long-term properties of cement-based and geopolymer materials exposed to outdoor environments, wet-dry cycles are usually used to accelerate their aging. The wet-dry cycling can simulate the effects of environmental factors on the long-term properties of the composites under natural conditions. Nowadays, the long-term properties of geopolymer materials are studied increasingly deeply. Unlike cement-based materials, geopolymers have better long-term properties due to their high early strength, fast hardening rate, and wide range of raw material sources. At the same time, natural cellulose fibers (NCFs) have the characteristics of abundant raw materials, low price, low carbon, and environmental protection. The use of NCFs as reinforcements of geopolymer matrix materials meets the requirements of sustainable development. In this paper, the types and properties of NCFs commonly used for geopolymer reinforcement and the polymerization mechanism of geopolymer matrix materials are summarized. By analyzing the properties of natural-cellulose-fiber-reinforced geopolymers (NCFRGs) under non-wet-dry cycles and NCFRGs under wet-dry cycles, the factors affecting the long-term properties of NCFRGs under wet-dry cycles are identified. Meanwhile, the degradation mechanism and mechanical properties of NCFRG composites after wet-dry cycles are analyzed. In addition, the relationship between the properties of composites and the change of microstructure of fiber degradation is further analyzed according to the results of microscopic analysis. Finally, the effects of wet-dry cycles on the properties of fibers and geopolymers are obtained.
为研究暴露于室外环境的水泥基材料和地质聚合物材料的长期性能,通常采用干湿循环来加速其老化。干湿循环可以模拟自然条件下环境因素对复合材料长期性能的影响。如今,对地质聚合物材料长期性能的研究越来越深入。与水泥基材料不同,地质聚合物因其早期强度高、硬化速度快和原材料来源广泛而具有更好的长期性能。同时,天然纤维素纤维(NCFs)具有原材料丰富、价格低廉、低碳环保的特点。使用NCFs作为地质聚合物基体材料的增强材料符合可持续发展的要求。本文总结了常用于地质聚合物增强的NCFs的类型和性能以及地质聚合物基体材料的聚合机理。通过分析非干湿循环条件下天然纤维素纤维增强地质聚合物(NCFRGs)和干湿循环条件下NCFRGs的性能,确定了影响干湿循环条件下NCFRGs长期性能的因素。同时,分析了干湿循环后NCFRG复合材料的降解机理和力学性能。此外,根据微观分析结果,进一步分析了复合材料性能与纤维降解微观结构变化之间的关系。最后,得出了干湿循环对纤维和地质聚合物性能的影响。