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氧化钕纳米颗粒对聚乙烯醇聚合物薄膜结构特性和介电性能的影响。

Effects of NdO Nanoparticles on the Structural Characteristics and Dielectric Properties of PVA Polymeric Films.

作者信息

Alshammari Khulaif, Alashgai Thamer, Alshammari Alhulw H, Abdelhamied Mostufa M, Alotibi Satam, Atta Ali

机构信息

Physics Department, College of Science, Jouf University, P.O. Box 2014, Sakaka 72388, Saudi Arabia.

Charged Particles Lab., Radiation Physics Department, National Center for Radiation Research and Technology (NCRRT), Egyptian Atomic Energy Authority (EAEA), Cairo 13759, Egypt.

出版信息

Polymers (Basel). 2023 Oct 14;15(20):4084. doi: 10.3390/polym15204084.

Abstract

Polyvinyl alcohol (PVA) and Neodymium (III) oxide (NdO) were combined to synthesized flexible innovative PVA/NdO polymer composite samples utilizing a solution casting approach for use in dielectric devices. The XRD, FTIR, and SEM methods are all investigated to characterize the composite films. In a frequency of 50 Hz to 5 MHz, the effects of additive NdO on the dielectric behavior of PVA were recorded. The PVA/NdO composite films were successfully fabricated, as shown by XRD and infrared spectroscopy. The scanning microscopy pictures showed that the NdO was loaded and distributed uniformly throughout the PVA. After the incorporation of NdO, the composite PVA/NdO has a conductivity of 6.82 × 10 S·cm, while the PVA has a conductivity of 0.82 × 10 S·cm. Another improvement is the decrease in the relaxation time from 14.2 × 10 s for PVA to 6.35 × 10 s for PVA/NdO, and an increase in the dielectric constant of 0.237 for PVA to 0.484 at a frequency of 100 Hz. The results showed that the composite samples have considerable changes as flexible films in different applications, including batteries and electronic circuits.

摘要

聚乙烯醇(PVA)和氧化钕(III)(NdO)相结合,采用溶液浇铸法合成了用于介电装置的柔性创新型PVA/NdO聚合物复合样品。对XRD、FTIR和SEM方法进行了研究,以表征复合薄膜。在50Hz至5MHz的频率范围内,记录了添加剂NdO对PVA介电行为的影响。XRD和红外光谱表明成功制备了PVA/NdO复合薄膜。扫描显微镜图片显示NdO负载并均匀分布在整个PVA中。掺入NdO后,复合PVA/NdO的电导率为6.82×10 S·cm,而PVA的电导率为0.82×10 S·cm。另一个改进是弛豫时间从PVA的14.2×10 s降至PVA/NdO的6.35×10 s,并且在100Hz频率下介电常数从PVA的0.237增加到0.484。结果表明,作为柔性薄膜,复合样品在包括电池和电子电路在内的不同应用中具有显著变化。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f466/10610177/1c8d94b74983/polymers-15-04084-g001.jpg

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