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用于能源和传感应用的纤维素基导电材料。

Cellulose-Based Conductive Materials for Energy and Sensing Applications.

作者信息

Wang Duan-Chao, Lei Sheng-Nan, Zhong Shenjie, Xiao Xuedong, Guo Qing-Hui

机构信息

Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou 310027, China.

Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311215, China.

出版信息

Polymers (Basel). 2023 Oct 19;15(20):4159. doi: 10.3390/polym15204159.

Abstract

Cellulose-based conductive materials (CCMs) have emerged as a promising class of materials with various applications in energy and sensing. This review provides a comprehensive overview of the synthesis methods and properties of CCMs and their applications in batteries, supercapacitors, chemical sensors, biosensors, and mechanical sensors. Derived from renewable resources, cellulose serves as a scaffold for integrating conductive additives such as carbon nanotubes (CNTs), graphene, metal particles, metal-organic frameworks (MOFs), carbides and nitrides of transition metals (MXene), and conductive polymers. This combination results in materials with excellent electrical conductivity while retaining the eco-friendliness and biocompatibility of cellulose. In the field of energy storage, CCMs show great potential for batteries and supercapacitors due to their high surface area, excellent mechanical strength, tunable chemistry, and high porosity. Their flexibility makes them ideal for wearable and flexible electronics, contributing to advances in portable energy storage and electronic integration into various substrates. In addition, CCMs play a key role in sensing applications. Their biocompatibility allows for the development of implantable biosensors and biodegradable environmental sensors to meet the growing demand for health and environmental monitoring. Looking to the future, this review emphasizes the need for scalable synthetic methods, improved mechanical and thermal properties, and exploration of novel cellulose sources and modifications. Continued innovation in CCMs promises to revolutionize sustainable energy storage and sensing technologies, providing environmentally friendly solutions to pressing global challenges.

摘要

纤维素基导电材料(CCMs)已成为一类具有广阔前景的材料,在能源和传感领域有多种应用。本文综述了CCMs的合成方法、性能及其在电池、超级电容器、化学传感器、生物传感器和机械传感器中的应用。纤维素来源于可再生资源,作为整合导电添加剂(如碳纳米管(CNTs)、石墨烯、金属颗粒、金属有机框架(MOFs)、过渡金属碳化物和氮化物(MXene)以及导电聚合物)的支架。这种结合产生了具有优异导电性的材料,同时保留了纤维素的生态友好性和生物相容性。在能量存储领域,CCMs由于其高表面积、优异的机械强度、可调节的化学性质和高孔隙率,在电池和超级电容器方面显示出巨大潜力。它们的柔韧性使其成为可穿戴和柔性电子器件的理想选择,有助于便携式能量存储以及将电子器件集成到各种基板方面的进展。此外,CCMs在传感应用中发挥着关键作用。它们的生物相容性使得可植入生物传感器和可生物降解环境传感器得以开发,以满足对健康和环境监测日益增长的需求。展望未来,本文强调需要可扩展的合成方法、改善的机械和热性能,以及探索新型纤维素来源和改性方法。CCMs的持续创新有望彻底改变可持续能量存储和传感技术,为紧迫的全球挑战提供环保解决方案。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef5b/10610528/1afa602a6d28/polymers-15-04159-g003.jpg

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