Ba(BS)(PS)：首个具有源于平面[BS]单元的强光学各向异性的碱土金属硫代硼酸盐-硫代磷酸盐。

Ba(BS)(PS): the first alkaline-earth metal thioborate-thiophosphate with strong optical anisotropy originating from planar [BS] units.

作者信息

Zhou Jiazheng, Wang Linan, Wang Hongshan, Luo Ling, Li Junjie, Yu Feng

机构信息

Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, China.

Research Center for Crystal Materials; CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, CAS; Xinjiang Key Laboratory of Electronic Information Materials & Devices, Urumqi 830011, China.

出版信息

Dalton Trans. 2023 Nov 14;52(44):16113-16117. doi: 10.1039/d3dt02807k.

DOI:10.1039/d3dt02807k

PMID:37899722

Abstract

The first alkaline-earth metal thioborate-thiophosphate Ba(BS)(PS) was designed from Ba(BO)(PO) by S-O substitution and fabricated experimentally. The [BS] pseudo-layers formed in the structure contribute to the strong optical anisotropy and a large birefringence of ∼0.11 at 1064 nm. The results enrich the structural and chemical diversity of chalcogenides.

摘要

首个碱土金属硫代硼酸盐-硫代磷酸盐Ba(BS)(PS)是通过S-O取代由Ba(BO)(PO)设计而来，并通过实验制备而成。结构中形成的[BS]假层导致了强烈的光学各向异性以及在1064nm处约0.11的大双折射。这些结果丰富了硫族化合物的结构和化学多样性。