Wang Shijie, Zhang Xue, Hao Shuyan, Qiao Jing, Wang Zhou, Wu Lili, Liu Jiurong, Wang Fenglong
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials Ministry of Education, Shandong University, Jinan, 250061, People's Republic of China.
School of Mechanical Engineering, Shandong University, Jinan, 250061, People's Republic of China.
Nanomicro Lett. 2023 Nov 17;16(1):16. doi: 10.1007/s40820-023-01244-w.
Carbon-based aerogels derived from biomass chitosan are encountering a flourishing moment in electromagnetic protection on account of lightweight, controllable fabrication and versatility. Nevertheless, developing a facile construction method of component design with carbon-based aerogels for high-efficiency electromagnetic wave absorption (EWA) materials with a broad effective absorption bandwidth (EAB) and strong absorption yet hits some snags. Herein, the nitrogen-doped magnetic-dielectric-carbon aerogel was obtained via ice template method followed by carbonization treatment, homogeneous and abundant nickel (Ni) and manganese oxide (MnO) particles in situ grew on the carbon aerogels. Thanks to the optimization of impedance matching of dielectric/magnetic components to carbon aerogels, the nitrogen-doped magnetic-dielectric-carbon aerogel (Ni/MnO-CA) suggests a praiseworthy EWA performance, with an ultra-wide EAB of 7.36 GHz and a minimum reflection loss (RL) of - 64.09 dB, while achieving a specific reflection loss of - 253.32 dB mm. Furthermore, the aerogel reveals excellent radar stealth, infrared stealth, and thermal management capabilities. Hence, the high-performance, easy fabricated and multifunctional nickel/manganese oxide/carbon aerogels have broad application aspects for electromagnetic protection, electronic devices and aerospace.
源自生物质壳聚糖的碳基气凝胶因其轻质、可控制备和多功能性,在电磁防护领域正迎来蓬勃发展的时刻。然而,开发一种利用碳基气凝胶进行组件设计的简便构建方法,以制备具有宽有效吸收带宽(EAB)和强吸收能力的高效电磁波吸收(EWA)材料,却遇到了一些阻碍。在此,通过冰模板法随后进行碳化处理获得了氮掺杂磁性介电碳气凝胶,均匀且丰富的镍(Ni)和氧化锰(MnO)颗粒在碳气凝胶上原位生长。得益于介电/磁性组件与碳气凝胶阻抗匹配的优化,氮掺杂磁性介电碳气凝胶(Ni/MnO-CA)展现出值得称赞的EWA性能,具有7.36 GHz的超宽EAB和−64.09 dB的最小反射损耗(RL),同时实现了−253.32 dB·mm的比反射损耗。此外,该气凝胶还展现出优异的雷达隐身、红外隐身和热管理能力。因此,高性能、易于制备且多功能的镍/氧化锰/碳气凝胶在电磁防护、电子设备和航空航天领域具有广泛的应用前景。