Muñoz-Castro Alvaro
Facultad de Ingeniería, Arquitectura y Diseño, Universidad San Sebastián, Bellavista 7, Santiago, 8420524, Chile.
Dalton Trans. 2023 Dec 5;52(47):17696-17700. doi: 10.1039/d3dt02693k.
The recent characterization of Au-PAP cluster can be viewed as a three-dimensional arrangement featuring four Au motifs. As a result, a new set of superatomic orbitals are built up from the superatomic shell of each constituent unit, denoted by 1S'1P'2S'1D'2P'1F' and, thus, referred to as a second-order superatomic shell structure. This favors the rationalization of larger species toward the formation of cluster-assembled materials of different sizes.
最近对金-磷簇的表征可被视为一种具有四个金 motif 的三维排列。因此，从每个组成单元的超原子壳层构建出一组新的超原子轨道，用 1S'1P'2S'1D'2P'1F' 表示，因而被称为二阶超原子壳层结构。这有利于对更大的物种进行合理化分析，以形成不同尺寸的簇组装材料。
