Li Sa, Liu Wentao, Xia Xiao-Feng
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu, 214122, China.
Industry and Information Technology Development Center of Yinan County, Linyi, Shandong, 276300, China.
Org Biomol Chem. 2023 Dec 6;21(47):9428-9432. doi: 10.1039/d3ob01729j.
Divergent aromatic ring nitrosation and nitration of aromatic amides are reported using NOBF as the electrophile under silver-catalyzed conditions. The reactions proceed efficiently with a wide range of compatible functionalities providing -position nitrosation products, deacylation nitrosation products, and nitration products from different tertiary and secondary aromatic amides.
