Phosphorescence resonance energy transfer from purely organic supramolecular assembly.

Phosphorescence energy transfer systems have been applied in encryption, biomedical imaging and chemical sensing. These systems exhibit ultra-large Stokes shifts, high quantum yields and are colour-tuneable with long-wavelength afterglow fluorescence (particularly in the near-infrared) under ambient conditions. This review discusses triplet-to-singlet PRET or triplet-to-singlet-to-singlet cascaded PRET systems based on macrocyclic or assembly-confined purely organic phosphorescence introducing the critical toles of supramolecular noncovalent interactions in the process. These interactions promote intersystem crossing, restricting the motion of phosphors, minimizing non-radiative decay and organizing donor-acceptor pairs in close proximity. We discuss the applications of these systems and focus on the challenges ahead in facilitating their further development.