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不同温度下耐高温锌合金牺牲阳极与套管的腐蚀研究

Corrosion Studies of Temperature-Resistant Zinc Alloy Sacrificial Anodes and Casing Pipe at Different Temperatures.

作者信息

Zhao Mifeng, Feng Shaobo, Hu Fangting, Geng Hailong, Li Xuanpeng, Long Yan, Feng Wenhao, Chen Zihan

机构信息

Oil and Gas Engineering Research Institute, Tarim Oilfield Company of CNPC, Korla 841000, China.

State Key Laboratory of Performance and Structural Safety of Petroleum Tubular Goods and Equipment Materials, CNPC Tubular Goods Research Institute, Xi'an 710077, China.

出版信息

Materials (Basel). 2023 Nov 10;16(22):7120. doi: 10.3390/ma16227120.

Abstract

In order to solve the problem of external corrosion of deep well casing in oil and gas fields, a new type of high-temperature-resistant zinc alloy sacrificial anode material was used. The temperature and corrosion resistance of the new anode material and TP140 casing were investigated by simulating the high-temperature working conditions of a deep well in an oil field using high-temperature and high-pressure corrosion tests and electrochemical tests. The results showed that at 100-120 °C, the corrosion rate of TP140 protected by a sacrificial anode was only one-tenth of that under unprotected conditions, and the minimum corrosion rate of TP140 protected by a sacrificial anode at 100 °C was 0.0089 mm/a. The results of the dynamic potential polarization curve showed that the corresponding corrosion current density of TP140 first increased and then decreased with the increase in temperature. The self-corrosion potential in sacrificial anode materials first increased and then decreased with the increase in temperature, and the potential difference with TP140 gradually decreased.

摘要

为解决油气田深井套管的外部腐蚀问题,采用了一种新型耐高温锌合金牺牲阳极材料。通过高温高压腐蚀试验和电化学试验模拟油田深井的高温工作条件,研究了新型阳极材料和TP140套管的耐温性及耐蚀性。结果表明,在100 - 120℃时,牺牲阳极保护下的TP140腐蚀速率仅为未保护条件下的十分之一,100℃时牺牲阳极保护下的TP140最小腐蚀速率为0.0089mm/a。动电位极化曲线结果表明,TP140的相应腐蚀电流密度随温度升高先增大后减小。牺牲阳极材料的自腐蚀电位随温度升高先增大后减小,与TP140的电位差逐渐减小。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/754b/10672601/76e1065568b3/materials-16-07120-g001.jpg

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