Huang Bo-Chin, Hung Fei-Yi
Department of Materials Science and Engineering, National Cheng Kung University, Tainan 701, Taiwan.
Materials (Basel). 2023 Nov 15;16(22):7176. doi: 10.3390/ma16227176.
CCDR 4043 Al alloys are an outstanding candidate for producing mechanical components for automotive or aircraft engines. Two experimental environments-sustained high temperature and repeated heating-cooling-were simulated in the laboratory to replicate the actual operating conditions of engine components. This research investigated the microstructural evolution, mechanical properties, and fracture characteristics of the 4043 Al alloy manufactured through the continuous casting direct rolling (CCDR) process under different post-processing conditions. The CCDR process combines continuous casting, billet heating, and subsequent continuous rolling in a single equipment of production line, enabling the mass production of Al alloy in a cost-effective and energy-efficient manner. In the present work, the 4043 alloy was subjected to two environmental conditions: a sustained high-temperature environment (control group) and a cyclic heating-cooling environment (experimental group). The maximum temperature was set to 200 °C in the experiment. The experimental results show that, in a sustained high temperature working environment, the strength and elongation of the CCDR 4043 Al alloy tend to be stable. The overall effect involves the Al matrix softening and the spheroidization of eutectic Si caused by prolonged exposure to high temperature. This can enhance its ductility while retaining a certain level of mechanical strength. Comparatively, in the working environment of cyclic heating-cooling (thermal cycle), the direction of Si diffusion was different in each cycle, thus leading to the formation of an irregular Ai-Si eutectic structure containing precipitated Si particles of different sizes. The two compositions of Al and Si with very different thermal expansion coefficients may induce defects at the sharp points of Si particles under repeated heating-cooling, thereby reducing the strength and ductility of the material. The results of this work can confirm that the fracture behavior of 4043 Al alloys is obviously controlled by the morphology of the precipitated eutectic Si. In addition, CCDR 4043 Al alloys are not suitable to be used in working environments with a thermal cycle. In practical applications, it is necessary to add traces of special elements or to employ other methods to achieve the purpose of spheroidizing the precipitated eutectic Si and Al-Fe-Si phases to avoid the deterioration of strength and ductility under cyclic heating. To date, no other literature has explored the changes in the microstructure and mechanical properties of CCDR 4043 Al alloys across various time scales under the aforementioned working environments. In summary, the findings provide valuable insights into the effect of thermal conditions on the properties and behavior of CCDR 4043 Al alloys, offering potential applications for it in various engineering fields, such as the automotive and aerospace industries.
CCDR 4043铝合金是生产汽车或飞机发动机机械部件的理想候选材料。在实验室中模拟了两种实验环境——持续高温和反复加热-冷却,以重现发动机部件的实际运行条件。本研究调查了通过连铸直接轧制(CCDR)工艺制造的4043铝合金在不同后处理条件下的微观结构演变、力学性能和断裂特性。CCDR工艺在一条生产线的单个设备中结合了连铸、坯料加热和后续的连续轧制,能够以经济高效且节能的方式大规模生产铝合金。在本工作中,4043合金经历了两种环境条件:持续高温环境(对照组)和循环加热-冷却环境(实验组)。实验中最高温度设定为200℃。实验结果表明,在持续高温工作环境下,CCDR 4043铝合金的强度和伸长率趋于稳定。总体效果包括由于长时间暴露在高温下导致铝基体软化和共晶硅球化。这可以提高其延展性,同时保持一定水平的机械强度。相比之下,在循环加热-冷却(热循环)的工作环境中,每个循环中硅的扩散方向不同,从而导致形成含有不同尺寸析出硅颗粒的不规则Al-Si共晶组织。铝和硅这两种热膨胀系数差异很大的成分在反复加热-冷却下可能会在硅颗粒的尖锐点处引发缺陷,从而降低材料的强度和延展性。本工作的结果可以证实,4043铝合金的断裂行为明显受析出共晶硅形态的控制。此外,CCDR 4043铝合金不适合在热循环的工作环境中使用。在实际应用中,有必要添加微量特殊元素或采用其他方法来实现析出共晶硅和Al-Fe-Si相球化的目的,以避免在循环加热下强度和延展性的恶化。迄今为止,尚无其他文献探讨在上述工作环境下CCDR 4043铝合金在不同时间尺度上微观结构和力学性能的变化。总之,这些发现为热条件对CCDR 4043铝合金性能和行为的影响提供了有价值的见解,为其在汽车和航空航天等各种工程领域的潜在应用提供了依据。