Zhou Changjian, Zhang Jiahao, Fu Yuqing, Dai Hui
School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng 224051, China.
College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China.
Molecules. 2023 Nov 18;28(22):7657. doi: 10.3390/molecules28227657.
The increase in carbon dioxide emissions has significantly impacted human society and the global environment. As carbon dioxide is the most abundant and cheap C1 resource, the conversion and utilization of carbon dioxide have received extensive attention from researchers. Among the many carbon dioxide conversion and utilization methods, the reverse water-gas conversion (RWGS) reaction is considered one of the most effective. This review discusses the research progress made in RWGS with various heterogeneous metal catalyst types, covering topics such as catalyst performance, thermodynamic analysis, kinetics and reaction mechanisms, and catalyst design and preparation, and suggests future research on RWGS heterogeneous catalysts.
二氧化碳排放量的增加对人类社会和全球环境产生了重大影响。由于二氧化碳是最丰富且廉价的C1资源，二氧化碳的转化和利用受到了研究人员的广泛关注。在众多二氧化碳转化和利用方法中，逆水煤气变换（RWGS）反应被认为是最有效的方法之一。本文综述了不同类型多相金属催化剂在逆水煤气变换反应方面取得的研究进展，涵盖催化剂性能、热力学分析、动力学及反应机理，以及催化剂设计与制备等主题，并对逆水煤气变换多相催化剂的未来研究提出了建议。
