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研究一种具有改进抗冲击性能的柔性聚氨酯弹性体。

Studying a Flexible Polyurethane Elastomer with Improved Impact-Resistant Performance.

作者信息

Fan Jitang, Chen Ang

机构信息

State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China.

出版信息

Polymers (Basel). 2019 Mar 12;11(3):467. doi: 10.3390/polym11030467.

Abstract

A flexible polyurethane elastomer (PUE) is studied, and the improved impact-resistant performance is revealed. Compressive stress⁻strain curves over a wide loading rate range were derived. Under static loading, the rubbery-like characteristics are demonstrated, which are flexible and hyperelastic, to process a large strain of about 60% followed by full recovery upon unloading. Under high-rate loadingcompared with the mechanical data of polyurethane elastomer (PUE) and polyurea (PUA) materials in the literature. Orderly parallel deformation bands were formed from carrying a large strain. The fibrils were found between deformation bands for enhancing the yield/plateau stress. A considerable plastic zone ahead of propagating crack with numerous crazes and microcracks was produced for realizing the dynamic strain energy absorption. This work presents a scientific innovation for developing outstanding impact-resistant polyurethane elastomers for transparent protection engineering.

摘要

研究了一种柔性聚氨酯弹性体(PUE),并揭示了其改进的抗冲击性能。得出了宽加载速率范围内的压缩应力-应变曲线。在静态加载下,表现出类似橡胶的特性,具有柔韧性和超弹性,可承受约60%的大应变,卸载后完全恢复。与文献中聚氨酯弹性体(PUE)和聚脲(PUA)材料的力学数据相比,在高速加载下,通过承受大应变形成了有序的平行变形带。在变形带之间发现了原纤维以提高屈服/平台应力。在扩展裂纹前方产生了一个相当大的具有大量银纹和微裂纹的塑性区,以实现动态应变能吸收。这项工作为开发用于透明防护工程的优异抗冲击聚氨酯弹性体提供了一项科学创新。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/981a/6473829/ffbd4dd11594/polymers-11-00467-g001.jpg

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