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On the Risk of F-Regioisomer Formation in the Copper-Free Radiofluorination of Aryliodonium Precursors.
Org Lett. 2023 Dec 8;25(48):8650-8654. doi: 10.1021/acs.orglett.3c03499. Epub 2023 Nov 27.
2
Hypervalent aryliodine compounds as precursors for radiofluorination.
J Labelled Comp Radiopharm. 2018 Mar;61(3):196-227. doi: 10.1002/jlcr.3570. Epub 2018 Feb 5.
3
An azeotropic drying-free approach for copper-mediated radiofluorination without addition of base.
J Labelled Comp Radiopharm. 2019 Mar;62(3):139-145. doi: 10.1002/jlcr.3705. Epub 2019 Feb 20.
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Synthesis of [ F]Fluoroarenes by Nucleophilic Radiofluorination of N-Arylsydnones.
Angew Chem Int Ed Engl. 2017 Oct 9;56(42):13006-13010. doi: 10.1002/anie.201707274. Epub 2017 Sep 7.
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No-carrier-added [18F]fluoroarenes from the radiofluorination of diaryl sulfoxides.
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Triflyl [F]Fluoride as a Solution for Base-Sensitive Late-Stage Nucleophilic Aromatic F-Fluorination Reactions.
Chemistry. 2025 Jan 9;31(2):e202403127. doi: 10.1002/chem.202403127. Epub 2024 Nov 26.
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Exploration of Directing-Group-Assisted, Copper-Mediated Radiofluorination and Radiosynthesis of [F]Olaparib.
ACS Med Chem Lett. 2023 Dec 18;15(1):116-122. doi: 10.1021/acsmedchemlett.3c00465. eCollection 2024 Jan 11.

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Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations.
Chem Rev. 2025 Mar 26;125(6):3440-3550. doi: 10.1021/acs.chemrev.4c00808. Epub 2025 Mar 7.

本文引用的文献

1
Transition metal free, late-stage, regiospecific, aromatic fluorination on a preparative scale using a KF/crypt-222 complex.
RSC Adv. 2018 Jun 11;8(38):21288-21291. doi: 10.1039/c8ra03757d. eCollection 2018 Jun 8.
2
Aryl(TMP)iodonium Tosylate Reagents as a Strategic Entry Point to Diverse Aryl Intermediates: Selective Access to Arynes.
Org Lett. 2021 Jun 18;23(12):4813-4817. doi: 10.1021/acs.orglett.1c01534. Epub 2021 May 25.
3
Hypervalent aryliodine compounds as precursors for radiofluorination.
J Labelled Comp Radiopharm. 2018 Mar;61(3):196-227. doi: 10.1002/jlcr.3570. Epub 2018 Feb 5.
4
5
A Selective C-H Deprotonation Strategy to Access Functionalized Arynes by Using Hypervalent Iodine.
Angew Chem Int Ed Engl. 2016 Jul 11;55(29):8431-4. doi: 10.1002/anie.201603222. Epub 2016 May 30.
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Unsymmetrical Aryl(2,4,6-trimethoxyphenyl)iodonium Salts: One-Pot Synthesis, Scope, Stability, and Synthetic Studies.
J Org Chem. 2016 Mar 4;81(5):1998-2009. doi: 10.1021/acs.joc.5b02833. Epub 2016 Feb 12.
7
(18)F-Labeling of Arenes and Heteroarenes for Applications in Positron Emission Tomography.
Chem Rev. 2016 Jan 27;116(2):719-66. doi: 10.1021/acs.chemrev.5b00493. Epub 2016 Jan 11.
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Reaction of arynes with sulfoxides.
Org Lett. 2015 Mar 6;17(5):1098-101. doi: 10.1021/ol5036326. Epub 2015 Feb 19.
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Tandem thia-Fries rearrangement--cyclisation of 2-(trimethylsilyl)phenyl trifluoromethanesulfonate benzyne precursors.
Chem Commun (Camb). 2013 Sep 7;49(69):7602-4. doi: 10.1039/c3cc44529a. Epub 2013 Jul 23.
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High beam current operation of a PETtrace™ cyclotron for 18F- production.
Appl Radiat Isot. 2012 Jun;70(6):922-30. doi: 10.1016/j.apradiso.2012.03.007. Epub 2012 Mar 18.

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