Sun Fengkai, Miao Man, Li Wenxue, Lan Xiao-Bing, Yu Jian-Qiang, Zhang Jian, An Zhenyu
College of Pharmacy, Ningxia Characteristic Traditional Chinese Medicine Modern Engineering Research Center, Ningxia Medical University, Yinchuan, Ningxia Hui Autonomous Region, China.
State Key Laboratory of Oncogenes and Related Genes, Key Laboratory of Cell Differentiation and Apoptosis of Chinese Ministry of Education, Shanghai Jiao Tong University School of Medicine, Shanghai, China.
Org Biomol Chem. 2024 Jan 17;22(3):472-476. doi: 10.1039/d3ob01867a.
An array of pyrrolo[1,2-]quinoxaline derivatives were achieved with moderate to good yields the electrochemical redox reaction, which includes the functionalization of C(sp)-H bonds and the construction of C-C and C-N bonds. In this atom economic reaction, THF was used as both a reactant and a solvent, and H was the sole by-product.
通过电化学氧化还原反应,以中等至良好的产率得到了一系列吡咯并[1,2 - ]喹喔啉衍生物,该反应包括C(sp)-H键的官能化以及C-C键和C-N键的构建。在这个原子经济反应中,四氢呋喃既作为反应物又作为溶剂,氢气是唯一的副产物。