Department of Geology and Mining, University of Rajshahi, Rajshahi 6205, Bangladesh.
Department of Geology and Mining, University of Rajshahi, Rajshahi 6205, Bangladesh.
J Hazard Mater. 2024 Mar 5;465:133214. doi: 10.1016/j.jhazmat.2023.133214. Epub 2023 Dec 12.
Eleven trace metals (Cd, Cr, Fe, Mn, Cu, Ni, Co, Zn, As, Pb, and Ag) in sediments of Bangladesh's ship breaking area were measured by an atomic absorption spectrometer to determine origin, contamination extent, spatial distributions, and associated ecological and human health hazards. This study found considerable quantities of Pb, Cd, Mn, Zn, and Cu when compared with standards and high levels of Pb, Cd, Zn, Cu, As, and Ag contamination according to pollution evaluation indices. Different indices indicate most of the sampling sites were highly polluted. However, spatial distribution maps indicate that trace metals were predominantly deposited in the northern and southern region. The ecological risk index revealed that Cd has the highest while Pb and As had moderate risk. Based on the health index values, Zn for both adults and children were higher than the safe limit while Mn, Pb, Cr, As, Fe, Cu, Ni, and Co for children were close to the threshold. The mean total carcinogenic risk values of Cr, As, and Ni for children and Ni for adults exceeded the permissible threshold. The cancer risk possibilities were further assessed using Monte Carlo simulation. Most trace metals have anthropogenic origins, which were attributed to ship breaking activities.
采用原子吸收光谱仪测定了孟加拉国船舶拆解区沉积物中的 11 种痕量金属(Cd、Cr、Fe、Mn、Cu、Ni、Co、Zn、As、Pb 和 Ag),以确定其来源、污染程度、空间分布以及与生态和人类健康危害相关的情况。与标准相比,本研究发现 Pb、Cd、Mn、Zn 和 Cu 的含量相当可观,根据污染评价指数,Pb、Cd、Zn、Cu、As 和 Ag 的污染水平较高。不同的指数表明,大多数采样点的污染程度很高。然而,空间分布地图表明,痕量金属主要沉积在北部和南部地区。生态风险指数表明 Cd 的风险最高,而 Pb 和 As 的风险为中等。根据健康指数值,成年人和儿童的 Zn 均高于安全限值,而儿童的 Mn、Pb、Cr、As、Fe、Cu、Ni 和 Co 则接近阈值。儿童的 Cr、As 和 Ni 以及成人的 Ni 的总致癌风险值平均值超过了允许阈值。还使用蒙特卡罗模拟进一步评估了癌症风险的可能性。大多数痕量金属具有人为来源,这归因于船舶拆解活动。