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污水污泥与生物质废物共热解制取生物燃料和生物炭:基于循环经济方法的综合可行性研究。

Co-pyrolysis of sewage sludge and biomass waste into biofuels and biochar: A comprehensive feasibility study using a circular economy approach.

机构信息

Department of Civil Engineering, University of British Columbia, 6250 Applied Science Lane, Vancouver, BC V6T 1Z4, Canada.

Department of Civil Engineering, University of British Columbia, 6250 Applied Science Lane, Vancouver, BC V6T 1Z4, Canada; Department of Agricultural Engineering, Cairo University, El-Gamma Street, Giza, 12613, Egypt.

出版信息

Chemosphere. 2024 Feb;350:141074. doi: 10.1016/j.chemosphere.2023.141074. Epub 2023 Dec 29.

Abstract

Enormous annual sewage sludge (SS) volumes pose global environmental challenges owing to contamination and significant greenhouse gas emissions. Here, we investigated the economic viability of co-pyrolyzing SS and biomass waste to produce biofuels (bio-oil and gas) and biochar. Net present worth (NPW) analysis, the sale product break-even price, and sludge handling price (SHP) were used to determine the profitability of co-pyrolysis compared with SS pyrolysis alone and conventional treatment methods. In this study, the sale prices of biochar based on quality (i.e., stability, carbon sequestration effectiveness, and heavy metal content) were estimated to be 2.24, 1.44, and 0.98 CAD/kg for high-, medium-, and low-grade biochar. The bio-oil prices, estimated based on the higher heating values of bio-oil and diesel, ranged from 0.80 to 1.22 CAD/kg. Sawdust (SD) and wheat straw (WS) were the chosen co-pyrolysis feedstocks, with four mixing ratios (20, 40, 60, and 80 wt%). Economically, SD (40 wt% mixing ratio) co-pyrolysis achieved the best performance, with a maximum NPW of 8.71 million CAD. SD single and co-pyrolysis were the only profitable scenarios. Moreover, SS single pyrolysis and WS co-pyrolysis exhibited higher profitability than conventional SS treatment methods, with SHPs of 65 and 40 CAD/1000 kg dry sludge, respectively. Sensitivity analysis highlighted the dependence of economic performance on biochar and bio-oil market value. This study offers the first economic analysis of this approach and enhances our understanding of the potential of co-pyrolysis for biofuel and biochar production, providing innovative solutions for the environmental challenges of SS disposal.

摘要

大量的年度污水污泥(SS)由于污染和大量温室气体排放而带来了全球性的环境挑战。在这里,我们研究了将 SS 和生物质废物共热解以生产生物燃料(生物油和气体)和生物炭的经济可行性。净现值(NPW)分析、销售产品盈亏平衡价格和污泥处理价格(SHP)用于确定与 SS 单独热解和常规处理方法相比,共热解的盈利能力。在本研究中,根据质量(即稳定性、固碳效果和重金属含量)估算了基于生物炭的销售价格,分别为高、中、低品位生物炭的 2.24、1.44 和 0.98 CAD/kg。根据生物油的高位发热值和柴油估算的生物油价格,范围为 0.80 至 1.22 CAD/kg。锯末(SD)和小麦秸秆(WS)是选择的共热解原料,共设置了四个混合比例(20、40、60 和 80 wt%)。从经济角度来看,SD(40 wt%混合比例)共热解表现最佳,NPW 达到 871 万加元。SD 单独和共热解是唯一盈利的方案。此外,SS 单独热解和 WS 共热解的盈利能力高于传统的 SS 处理方法,SHP 分别为 65 和 40 CAD/1000 kg 干污泥。敏感性分析强调了经济性能对生物炭和生物油市场价值的依赖性。本研究首次对这种方法进行了经济分析,增强了我们对共热解生产生物燃料和生物炭的潜力的理解,为 SS 处理的环境挑战提供了创新的解决方案。

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