Recent advances in TEMPO-oxidized cellulose nanofibers: Oxidation mechanism, characterization, properties and applications.

Cellulose is the richest renewable polymer source on the earth. TEMPO-mediated oxidized cellulose nanofibers are deduced from enormously available wood biomass and functionalized with carboxyl groups. The preparation procedure of TOCNFs is more environmentally friendly compared to other cellulose, for example, MFC and CNCs. Due to the presence of functional carboxyl groups, TOCNF-based materials have been studied widely in different fields, including biomedicine, wastewater treatment, bioelectronics and others. In this review, the TEMPO oxidation mechanism, the properties and applications of TOCNFs are elaborated. Most importantly, the recent advanced applications and the beneficial role of TOCNFs in the various abovementioned fields are discussed. Furthermore, the performances and research progress on the fabrication of TOCNFs are summarized. It is expected that this timely review will help further research on the invention of novel material from TOCNFs and its applications in different advanced fields, including biomedicine, bioelectronics, wastewater treatment, and the energy sector.