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采用新型壳聚糖-镍铁氧体纳米吸附剂从果汁样品中去除日落黄的建模。

Modeling sunset yellow removal from fruit juice samples by a novel chitosan-nickel ferrite nano sorbent.

机构信息

Department of Environmental Health Engineering, Food Safety Division, School of Public Health, Tehran University of Medical Sciences, Tehran, Iran.

Department of Pharmaceutical Biotechnology, Faculty of Pharmacy, Tehran University of Medical Sciences, Tehran, Iran.

出版信息

Sci Rep. 2024 Jan 2;14(1):208. doi: 10.1038/s41598-023-50284-0.

DOI:10.1038/s41598-023-50284-0
PMID:38167448
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10762053/
Abstract

Analysis of food additives is highly significant in the food industry and directly related to human health. This investigation into the removal efficiency of sunset yellow as an azo dye in fruit juices using Chitosan-nickel ferrite nanoparticles (Cs@NiFeO NPs). The nanoparticles were synthesized and characterized using various techniques. The effective parameters for removing sunset yellow were optimized using the response surface methodology (RSM) based on the central composite design (CCD). Under the optimum conditions, the highest removal efficiency (94.90%) was obtained for the initial dye concentration of 26.48 mg L at a pH of 3.87, a reaction time of 67.62 min, and a nanoparticle dose of 0.038 g L. The pseudo-second-order kinetic model had a better fit for experimental data (R = 0.98) than the other kinetic models. The equilibrium adsorption process followed the Freundlich isotherm model with a maximum adsorption capacity of 212.766 mg g. The dye removal efficiency achieved for industrial and traditional fruit juice samples (91.75% and 93.24%), respectively, confirmed the method's performance, feasibility, and efficiency. The dye adsorption efficiency showed no significant decrease after five recycling, indicating that the sorbent has suitable stability in practical applications. variousThe synthesized nanoparticles can be suggested as an efficient sorbent to remove the sunset yellow dye from food products.

摘要

食品添加剂分析在食品工业中具有重要意义,直接关系到人类健康。本研究采用壳聚糖-镍铁氧体纳米粒子(Cs@NiFeO NPs)去除果汁中的偶氮染料日落黄。采用多种技术合成并表征了纳米粒子。利用响应面法(RSM)基于中心复合设计(CCD)优化了去除日落黄的有效参数。在最佳条件下,当初始染料浓度为 26.48mg/L、pH 值为 3.87、反应时间为 67.62min 和纳米粒子剂量为 0.038g/L 时,获得了最高去除效率(94.90%)。伪二阶动力学模型比其他动力学模型更能拟合实验数据(R=0.98)。平衡吸附过程遵循 Freundlich 等温吸附模型,最大吸附容量为 212.766mg/g。工业和传统果汁样品的染料去除效率分别达到 91.75%和 93.24%,证实了该方法的性能、可行性和效率。五次循环后,染料吸附效率没有明显下降,表明该吸附剂在实际应用中具有良好的稳定性。合成的纳米粒子可以作为一种有效的吸附剂,用于去除食品中的日落黄染料。

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