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新型多源危险废物共处置系统焚烧飞灰的特性及其稳定化:固化稳定化的现场研究。

Characterization and stabilization of incineration fly ash from a new multi-source hazardous waste co-disposal system: field-scale study on solidification and stabilization.

机构信息

School of Mechanical and Power Engineering, Nanjing Tech University, Nanjing, 211800, China.

School of Environmental Science and Engineering, Nanjing Tech University, Nanjing, 211800, China.

出版信息

Environ Sci Pollut Res Int. 2024 Jan;31(5):7712-7727. doi: 10.1007/s11356-023-31677-0. Epub 2024 Jan 3.

DOI:10.1007/s11356-023-31677-0
PMID:38170352
Abstract

The multi-source hazardous waste co-disposal system, a recent innovation in the industry, offers an efficient approach for hazardous waste disposal. The incineration fly ash (HFA) produced by this system exhibits characteristics distinct from those of typical incineration fly ash, necessitating the use of adjusted disposal methods. This study examined the physicochemical properties, heavy metal content, heavy metal leaching concentration, and dioxin content of HFA generated by the new co-disposal system and compared them with those of conventional municipal waste incineration fly ash. This study investigated the solidification and stabilization of HFA disposal using the organic agent sodium diethyl dithiocarbamate combined with cement on a field scale. The findings revealed significant differences in the structure, composition, and dioxin content of HFA and FA; HFA contained substantially lower levels of dioxins than FA did. Concerning the heavy metal content and leaching; HFA exhibited an unusually high concentration of zinc, surpassing the permitted emission limits, making zinc content a critical consideration in HFA disposal. After stabilization and disposal, the heavy metal leaching and dioxin content of HFA can meet landfill disposal emission standards when a 1% concentration of 10% sodium diethyldithiocarbamate (DDTC) and 150% silicate cement were employed. These results offer valuable insights into the disposal of fly ash resulting from incineration of mixed hazardous waste.

摘要

多源危险废物共处置系统是该行业的一项新创新,为危险废物处置提供了一种有效的方法。该系统产生的焚烧飞灰(HFA)具有不同于典型焚烧飞灰的特性,需要采用调整后的处置方法。本研究考察了新型共处置系统产生的 HFA 的物理化学性质、重金属含量、重金属浸出浓度和二恶英含量,并将其与传统城市垃圾焚烧飞灰进行了比较。本研究在现场规模上研究了使用有机试剂二乙基二硫代氨基甲酸钠(DDTC)与水泥结合对 HFA 进行固化和稳定化的方法。研究结果表明,HFA 和 FA 在结构、组成和二恶英含量方面存在显著差异;HFA 中二恶英的含量明显低于 FA。关于重金属含量和浸出;HFA 中的锌浓度异常高,超过了允许的排放限值,因此锌含量是 HFA 处置的一个关键考虑因素。经过稳定化和处置后,当使用 1%浓度的 10%二乙基二硫代氨基甲酸钠(DDTC)和 150%硅酸盐水泥时,HFA 的重金属浸出和二恶英含量可以达到填埋处置的排放标准。这些结果为混合危险废物焚烧飞灰的处置提供了有价值的见解。

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