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导电聚合物@石墨烯复合材料增强的微波吸收性能以对抗电磁辐射污染:绿色电磁干扰屏蔽

Enhanced microwave absorption properties of conducting polymer@graphene composite to counteract electromagnetic radiation pollution: green EMI shielding.

作者信息

Kumari Suman, Dalal Jasvir, Kumar Anand, Pal Rishi, Chahal Ritu, Ohlan Anil

机构信息

Department of Physics, Chaudhary Ranbir Singh University Jind 126102 India

Department of Physics, Maharani Kishori Jat Kanya Mahavidyalaya Rohtak 124001 India.

出版信息

RSC Adv. 2024 Jan 2;14(1):662-676. doi: 10.1039/d3ra07245b.

Abstract

Conducting polymers have been thoroughly investigated and found to have extensive applications in the fields of microwave absorption and electromagnetic (EM) shielding owing to their distinctive characteristics and adaptability. In the present work, conducting polymer (PEDOT and polyaniline) and graphene composites were prepared an chemical polymerization technique. Further, these composite materials were characterized to determine their potential to address the issue of EM radiation pollution in the microwave frequency (12.4 GHz to 18 GHz). The PEDOT/graphene composites exhibited significant shielding effectiveness of up to 46.53 dB, achieving a green index () of 1.17. Also, absorption was observed to be the dominant shielding mechanism in all the samples owing to significant dielectric losses (''/' ≈ 1.9-3.1) and microwave conductivity ( = 19.9-73.6 S m) in the samples at 18 GHz. Both dielectric loss and conduction loss occurred because of the strong interactions involving polarization, charge propagation, and the creation of conductive routes through the incorporation of graphene in the polymer matrix. These properties/shielding results indicate the potential of the composites to be used as lightweight EM shielding materials. These materials are suitable shield materials for electronic devices to protect them from harmful electromagnetic radiation, making them vital in various applications.

摘要

导电聚合物已得到充分研究,由于其独特的特性和适应性,在微波吸收和电磁(EM)屏蔽领域有着广泛的应用。在本工作中,采用化学聚合技术制备了导电聚合物(聚3,4-乙撑二氧噻吩和聚苯胺)与石墨烯的复合材料。此外,对这些复合材料进行了表征,以确定它们解决微波频率(12.4 GHz至18 GHz)下电磁辐射污染问题的潜力。聚3,4-乙撑二氧噻吩/石墨烯复合材料表现出高达46.53 dB的显著屏蔽效能,绿色指数()为1.17。此外,由于在18 GHz时样品中存在显著的介电损耗(''/'≈1.9 - 3.1)和微波电导率( = 19.9 - 73.6 S m),观察到吸收是所有样品中的主要屏蔽机制。介电损耗和传导损耗的发生都是由于涉及极化、电荷传播以及通过在聚合物基体中引入石墨烯形成导电路径的强相互作用。这些特性/屏蔽结果表明该复合材料有潜力用作轻质电磁屏蔽材料。这些材料是用于电子设备的合适屏蔽材料,可保护它们免受有害电磁辐射,使其在各种应用中至关重要。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/757f/10760626/d7b31727e6f6/d3ra07245b-s1.jpg

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