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一种具有良好水溶性的红色荧光碳点,用于实际样品中铝的快速检测。

A red fluorescent carbon dots with good water solubility for rapid detection of Al in actual samples.

作者信息

Zhao Jingyuan, Yao Jie, Wang Yingqi, Wang Ning, Wang Jianhua

机构信息

The First Clinical Medical School, Shanxi Medical University, Taiyuan, China.

Department of Basic Medicine, Shanxi Medical University, Jinzhong, China.

出版信息

Luminescence. 2024 Feb;39(2):e4666. doi: 10.1002/bio.4666. Epub 2024 Jan 5.

Abstract

We developed a facile strategy for the fabrication of red fluorescent carbon nanodots (R-CDs) and demonstrated their applications for Al sensing. Red-emission carbon dots (CDs) were synthesized using a simple hydrothermal treatment with citric acid and urea as precursors, manifesting intriguing red-emission behaviour at 610 nm. With increasing Al concentration, the fluorescence band at 610 nm decreased gradually. Monitoring the intrinsic fluorescence variation (I ), as-prepared CDs were developed as an effective platform for fluorescent Al sensing, with a linear range of 0.5-60.0 μM and a detection limit of 3.0 nM. More importantly, R-CDs have been applied successfully to the analysis of Al in actual samples with satisfactory recoveries in the range 97.12-102.05%, which indicated that obtained CDs could be implemented as an effective tool for the identification and detection of Al in actual samples.

摘要

我们开发了一种简便的制备红色荧光碳纳米点(R-CDs)的策略,并展示了其在铝传感方面的应用。以柠檬酸和尿素为前驱体,通过简单的水热法合成了发红光的碳点(CDs),在610nm处表现出有趣的发红光行为。随着铝浓度的增加,610nm处的荧光带逐渐降低。通过监测固有荧光变化(I),所制备的CDs被开发成为一种有效的荧光铝传感平台,线性范围为0.5-60.0μM,检测限为3.0 nM。更重要的是,R-CDs已成功应用于实际样品中铝的分析,回收率在97.12-102.05%范围内,令人满意,这表明所获得的CDs可作为一种有效的工具用于实际样品中铝的鉴定和检测。

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