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用于低渗透油藏一致性控制的预制亚微米交联聚合物线圈的制备

Preparation of Preformed Submicron Crosslinked Polymer Coils for Conformance Control in Low-Permeability Reservoirs.

作者信息

Liu Jianwei, Peng Bo

机构信息

Beijing Key Laboratory for Greenhouse Gas Storage and CO2-EOR, Unconventional Petroleum Research Institute, China University of Petroleum-Beijing, Beijing 102249, China.

出版信息

Polymers (Basel). 2023 Dec 21;16(1):39. doi: 10.3390/polym16010039.

Abstract

With the increasing development of low-permeability reservoirs, the significance of conformance control treatment has risen considerably. To address the conflict between injectability and plugging performance, as well as to enhance the deep migration capacity of conformance control agents, preformed submicron crosslinked polymer coils (SCPCs) have been manufactured using aqueous solution dispersion polymerization. Fourier transform infrared and scanning electron microscopy were employed to examine the chemical structure and micromorphology, while particle size distribution, zeta potential, rheological, and filtration properties were analyzed. The effectiveness of conformance control was confirmed through the parallel core displacement. The effective particle size of SCPCs was at a submicron level (500800 nm). SCPCs exhibit a transitional threshold concentration between gel and sol states (0.25 wt%0.5 wt%). SCPCs can efficiently block the 1.2 μm microporous filter membrane. The filtration time is up to 67.8 min. SCPCs can improve the water absorption rate of lower permeability cores from 21.21% to 57.89% with a permeability difference of 5. Therefore, SCPCs have good injectability, plugging performance, and deep migration capacity and can be used for conformance control in low-permeability reservoirs.

摘要

随着低渗透油藏开发程度的不断提高,调剖治理的意义日益凸显。为解决注入性与封堵性能之间的矛盾,提高调剖剂的深部运移能力,采用水溶液分散聚合法制备了预交联亚微米聚合物微线圈(SCPCs)。利用傅里叶变换红外光谱和扫描电子显微镜对其化学结构和微观形貌进行了表征,分析了其粒径分布、zeta电位、流变性能和过滤性能。通过平行岩心驱替实验验证了调剖效果。SCPCs的有效粒径处于亚微米级(500800 nm)。SCPCs在凝胶态和溶胶态之间存在转变临界浓度(0.25 wt%0.5 wt%)。SCPCs能够有效封堵1.2μm的微孔滤膜,过滤时间长达67.8 min。对于渗透率级差为5的低渗透岩心,SCPCs可使岩心吸水率从21.21%提高到57.89%。因此,SCPCs具有良好的注入性、封堵性能和深部运移能力,可用于低渗透油藏的调剖治理。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5c0b/10780422/2efe1adcb5a7/polymers-16-00039-g001.jpg

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