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欧盟生物质废弃物利用的可能选择:热解炭、热值和灰分含量

Possible Options for Utilization of EU Biomass Waste: Pyrolysis Char, Calorific Value and Ash Content.

作者信息

Iwanek Nee Wilczkowska Ewa M, Nietrzeba Urszula, Pietras Marta, Marciniak Aleksandra, Głuski Gustaw, Hupka Jakub, Szymajda Miłosz, Kamiński Jakub, Szerewicz Cezary, Goździk Aleksandra, Kirk Donald W

机构信息

Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland.

Department of Chemical Engineering and Applied Chemistry, University of Toronto, 200 College Street, Toronto, ON M5S 3E5, Canada.

出版信息

Materials (Basel). 2023 Dec 31;17(1):226. doi: 10.3390/ma17010226.

Abstract

The application of biomass as a co-feed in coal power plants and in standalone biomass power plants, as well as in char production for soil remediation, is a currently important issue. This paper reports on the investigation of biochar formation from agricultural waste crops that are used for soil upgrading, but which do not meet the standards of EU crops, as well as largescale food processing waste. These were compared to test results from basket willow, which is commonly used for energy generation. Food industry waste is often produced in cities on a large scale and is generally easier to process due to lack of other stream components. The key parameters, namely, the content of volatiles, energy content of the formed biochar and the composition of the ash, were determined for a number of herbaceous materials locally available in the European Union. All of them can be used as a cheap source of biochar. A novel procedure of capturing volatiles and hence minimizing the PAH content in the biochar, as well as enabling the recovery of energy from the volatiles is presented. Knowledge of the composition and form of elements in ash is very important for designing ash management systems if co-combustion is implemented. The aim of this study was to determine if the types of biomass are better suited for biochar production or energy generation.

摘要

生物质作为混燃燃料应用于煤电厂和独立生物质电厂,以及用于土壤修复的焦炭生产,是当前一个重要问题。本文报道了对用于土壤改良但不符合欧盟作物标准的农业废弃作物以及大规模食品加工废弃物生成生物炭的研究。将这些与常用于能源生产的柳条篮的测试结果进行了比较。食品工业废弃物通常在城市大量产生,并且由于缺乏其他流成分,一般更易于处理。针对欧盟当地可得的多种草本材料,测定了关键参数,即挥发物含量、生成生物炭的能量含量以及灰分组成。所有这些材料都可作为廉价的生物炭来源。本文提出了一种捕获挥发物从而使生物炭中多环芳烃含量降至最低,并能从挥发物中回收能量的新方法。如果实施共燃烧,了解灰分中元素的组成和形态对于设计灰分管理系统非常重要。本研究的目的是确定生物质类型是否更适合生物炭生产或能源生产。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f892/10780033/c180da4c5d02/materials-17-00226-g004.jpg

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