Teymoori Maryam, Pourshamsian Khalil
Department of Chemistry, Tonekabon Branch, Islamic Azad University, Tonekabon, Iran.
Heliyon. 2023 Dec 5;10(1):e23301. doi: 10.1016/j.heliyon.2023.e23301. eCollection 2024 Jan 15.
Today, the use of X-rays in diagnosing and sometimes treating patients is inevitable. Despite the many benefits of using X-rays in medical and other sciences, the harmful effects of this radiation on human tissue should not be neglected. One of the best ways to prevent the harmful effects of X-rays on the human body is to use appropriate covers against these rays. It seems that it is necessary to find effective particles to weaken X-rays and choose a suitable substrate with high mechanical resistance to scatter particles in it. In this study, the synthesis of SnO nanoparticles from SnCl.2HO precursor and BaSO nanoparticles from BaCl.2HO precursor using neem tree extract (Azadirachta indica) as a reducing and stabilizing agent is reported. After the synthesis of nanoparticles, their structure was investigated by X-ray diffraction, scanning electron microscopy and energy dispersive X-ray analysis. Then the desired composite and nanocomposite were prepared in the polymer substrate. The sheets were prepared using an extruder and then a hot hydraulic press. The output sheets had a thickness of 1 mm. The structural characteristics of the produced sheets such as surface morphology, density of prepared composites, mechanical properties, thermal gravimetric analysis and retention of loaded particles after three times washes were investigated. The X-ray attenuation capability of each sample was evaluated by calculating the linear attenuation coefficient for each prepared sample. The results show that all sheets filled with tin and barium micro and nano particles have more X-ray attenuation capabilities than pure polymer. Among the prepared sheets, the nanocomposite prepared from low-density polyethylene (77 %) + SnO (10 %) + BaSO (10 %) + multi-walled carbon nanotubes (3 %) showed the highest X-ray attenuation.
如今,在诊断甚至有时治疗患者时使用X射线已不可避免。尽管在医学及其他学科中使用X射线有诸多益处,但这种辐射对人体组织的有害影响不容忽视。预防X射线对人体产生有害影响的最佳方法之一是使用合适的射线防护物。似乎有必要找到有效的粒子来削弱X射线,并选择一种具有高机械抗性以散射其中粒子的合适基质。在本研究中,报道了以印楝树提取物(印楝)作为还原剂和稳定剂,由SnCl·2H₂O前驱体制备SnO纳米粒子以及由BaCl·2H₂O前驱体制备BaSO₄纳米粒子。纳米粒子合成后,通过X射线衍射、扫描电子显微镜和能量色散X射线分析对其结构进行了研究。然后在聚合物基质中制备所需的复合材料和纳米复合材料。使用挤出机然后通过热液压机制备板材。产出的板材厚度为1毫米。对所生产板材的结构特性进行了研究,如表面形态、制备复合材料的密度、机械性能、热重分析以及三次洗涤后负载粒子的保留情况。通过计算每个制备样品的线性衰减系数来评估每个样品的X射线衰减能力。结果表明,所有填充有锡和钡微米及纳米粒子的板材比纯聚合物具有更强的X射线衰减能力。在所制备的板材中,由低密度聚乙烯(77%)+SnO(10%)+BaSO₄(10%)+多壁碳纳米管(3%)制备的纳米复合材料显示出最高的X射线衰减能力。