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纳米氧化镉/高密度聚乙烯复合材料的伽马衰减系数

Gamma Attenuation Coefficients of Nano Cadmium Oxide/High density Polyethylene Composites.

作者信息

El-Khatib Ahmed M, Abbas Mahmoud I, Elzaher Mohamed Abd, Badawi Mohamed S, Alabsy Mahmoud T, Alharshan Gharam A, Aloraini Dalal A

机构信息

Physics Department, Faculty of Science, Alexandria University, 21511, Alexandria, Egypt.

Department of Basic and Applied Science, Faculty of Engineering, Arab Academy for Science, Technology P.O 1129, Alexandria, Egypt.

出版信息

Sci Rep. 2019 Nov 5;9(1):16012. doi: 10.1038/s41598-019-52220-7.

Abstract

In the present work, high density polyethylene (HDPE) matrix mixed with micro-sized and nano-sized Cadmium oxide (CdO) particles of different concentrations were prepared by compression molding technique. The aim of the study is to investigate the effect of particle size and weight percentage of CdO particles on the gamma radiation shielding ability of CdO/HDPE composites. The mass attenuation coefficients of pure HDPE, micro-CdO/HDPE and nano-CdO/HDPE composites were evaluated at photon energies ranging from 59.53 keV to 1408.01 keV using standard radioactive point sources [Am, Ba, Cs, Co and Eu]. Adding micro and nano CdO particles to the HDPE matrix clearly increases the mass attenuation coefficients of the composites and the improvement is more significant at low γ-ray energies. The effect of particle size of CdO filler has an important role on the shielding ability of the composite. The experimental results reveal that, the composites filled with nano-CdO have better γ-radiation shielding ability compared to that filled with micro-CdO at the same weight fraction. A relative increase rate of about 16% is obtained with nano-CdO content of 40 wt% at 59.53 keV, which attributed to the higher probability of interaction between γ-rays and nanoparticles. From this study, it can be concluded that nano-CdO has a good performance shielding characteristic than micro-CdO in HDPE based radiation shielding material.

摘要

在本工作中,通过压缩成型技术制备了混合有不同浓度微米级和纳米级氧化镉(CdO)颗粒的高密度聚乙烯(HDPE)基体。本研究的目的是研究CdO颗粒的粒径和重量百分比对CdO/HDPE复合材料伽马辐射屏蔽能力的影响。使用标准放射性点源[镅、钡、铯、钴和铕]在59.53 keV至1408.01 keV的光子能量范围内评估了纯HDPE、微米CdO/HDPE和纳米CdO/HDPE复合材料的质量衰减系数。向HDPE基体中添加微米和纳米CdO颗粒明显提高了复合材料的质量衰减系数,并且在低γ射线能量下这种提高更为显著。CdO填料的粒径对复合材料的屏蔽能力有重要作用。实验结果表明,在相同重量分数下,填充纳米CdO的复合材料比填充微米CdO的复合材料具有更好的γ辐射屏蔽能力。在59.53 keV下,纳米CdO含量为40 wt%时可获得约16%的相对增加率,这归因于γ射线与纳米颗粒之间相互作用的概率更高。从本研究可以得出结论,在基于HDPE的辐射屏蔽材料中,纳米CdO比微米CdO具有更好的屏蔽性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb95/6831599/26c03b203bbd/41598_2019_52220_Fig1_HTML.jpg

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