Azad Armin, Sheikh M Neaz, Hai Faisal I
Strategic Water Infrastructure Laboratory, School of Civil, Mining, Environmental and Architectural Engineering, University of Wollongong, Wollongong, NSW 2522, Australia.
School of Civil, Mining, Environmental and Architectural Engineering, University of Wollongong, Wollongong, NSW 2522, Australia.
Water Res. 2024 Mar 1;251:121101. doi: 10.1016/j.watres.2024.121101. Epub 2024 Jan 2.
Stormwater can carry pollutants accumulated on impervious surfaces in urban areas into natural water bodies in absence of stormwater quality improvement devices. Pervious concrete (PC) pavement is one of the low-impact development practices introduced for urban flooding prevention and stormwater pollution reduction. PC removes various types of water contaminants. Mechanisms contributing to the water pollution removal capacity of PC can be categorized into three groups: physical, chemical, and biological. Properties of PC such as permeability, porosity, thickness, and adsorption capacity influence removal of all contaminants, although their impact might differ depending on the pollutant properties. Chemical mechanisms include precipitation, co-precipitation, ion and ligand exchange, complexation, diffusion, and sorption. Bulk organics and nutrients are removed primarily by biodegradation. Physical filtration is the primary mechanism to retain suspended solids, although biological activities may have a minor contribution. Release of calcium (Ca) and hydroxide (OH) from hardened cement elevates the effluent pH, which is an environmental concern. However, the pH elevation is also the prime contributor to heavy metals and nutrients removal through precipitation. Specific cementitious materials (e.g., Pozzolans and nanoparticles) and carbonation curing approach are recommended to control effluent pH elevation. Complexation, diffusion, ion solubility, and stability constants are other mechanisms and parameters that influence heavy metal removal. Organic matter availability, electrostatic attraction, temperature, pH, contact time, specific surface area, and roughness of PC pores contribute to the pathogen removal process. Although PC has been found promising in removing various water pollutants, limited salinity removal can be achieved due to the inherent release of Caand OH from PC.
在没有雨水水质改善装置的情况下,雨水会将城市地区不透水表面积累的污染物带入天然水体。透水混凝土(PC)路面是为预防城市内涝和减少雨水污染而引入的低影响开发措施之一。PC能去除各种类型的水污染物。PC去除水污染的机制可分为三类:物理、化学和生物。PC的渗透率、孔隙率、厚度和吸附能力等特性会影响所有污染物的去除,尽管它们的影响可能因污染物特性而异。化学机制包括沉淀、共沉淀、离子和配体交换、络合、扩散和吸附。大分子有机物和营养物质主要通过生物降解去除。物理过滤是保留悬浮固体的主要机制,尽管生物活动可能有较小贡献。硬化水泥中钙(Ca)和氢氧根(OH)的释放会提高出水pH值,这是一个环境问题。然而,pH值升高也是通过沉淀去除重金属和营养物质的主要因素。建议使用特定的胶凝材料(如火山灰和纳米颗粒)和碳化养护方法来控制出水pH值升高。络合、扩散、离子溶解度和稳定性常数是影响重金属去除的其他机制和参数。有机物的可用性、静电吸引力、温度、pH值、接触时间、比表面积和PC孔隙的粗糙度有助于病原体的去除过程。尽管PC在去除各种水污染物方面很有前景,但由于PC中Ca和OH的固有释放,盐分去除效果有限。