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解锁棉秆作为可再生纤维素资源的潜力:进展与新兴应用综述。

Unlocking the potential of cotton stalk as a renewable source of cellulose: A review on advancements and emerging applications.

机构信息

School of Biological and Environmental Sciences, Shoolini University of Biotechnology and Management Sciences, Solan 173229, India.

School of Biological and Environmental Sciences, Shoolini University of Biotechnology and Management Sciences, Solan 173229, India.

出版信息

Int J Biol Macromol. 2024 Mar;261(Pt 2):129456. doi: 10.1016/j.ijbiomac.2024.129456. Epub 2024 Jan 17.

DOI:10.1016/j.ijbiomac.2024.129456
PMID:38237828
Abstract

Cotton stalk (CS) is a global agricultural residue, with an annual production of approximately 50 million tons, albeit with limited economic significance. The utilization of cellulose derived from CS has gained significant attention in green nanomaterial technologies. This interest stems from its unique properties, including biocompatibility, low density, minimal thermal expansion, eco-friendliness, renewability, and its potential as an alternative source for chemicals, petroleum, and biofuels. In this review, we delve into various extraction and characterization methods, the physicochemical attributes, recent advancements, and the applications of cellulose extracted from CS. Notably, the steam explosion method has proven to yield the highest cellulose content (82 %) from CS. Moreover, diverse physicochemical properties of cellulose can be obtained through different extraction techniques. Sulfuric acid hydrolysis, for instance, yields nanocrystalline cellulose fibers measuring 10-100 nm in width and 100-850 nm in length. Conversely, the steam explosion method yields cellulose fibers with dimensions of 10.7 μm in width and 1.2 mm in length. CS-derived products, including biochar, aerogel, dye adsorbents, and reinforcement fillers, find applications in various industries, such as environmental remediation and biodegradable packaging. This is primarily due to their ready availability, cost-effectiveness, and sustainable nature.

摘要

棉秆(CS)是一种全球农业废弃物,每年的产量约为 5000 万吨,但经济意义有限。源自 CS 的纤维素的利用在绿色纳米材料技术中引起了广泛关注。这种兴趣源于其独特的性质,包括生物相容性、低密度、最小热膨胀、环保、可再生性,以及作为化学品、石油和生物燃料的替代来源的潜力。在这篇综述中,我们深入探讨了从 CS 中提取和表征纤维素的各种方法、纤维素的物理化学特性、最新进展以及其在各个领域的应用。值得注意的是,蒸汽爆破法已被证明是从 CS 中提取纤维素的最高产率方法(82%)。此外,通过不同的提取技术可以获得不同的纤维素物理化学性质。例如,硫酸水解可得到宽度为 10-100nm 、长度为 100-850nm 的纳米晶纤维素纤维。相比之下,蒸汽爆破法得到的纤维素纤维的宽度为 10.7μm 、长度为 1.2mm。CS 衍生产品,包括生物炭、气凝胶、染料吸附剂和增强填料,在环境修复和可生物降解包装等各个行业得到了应用。这主要是由于其易于获取、成本效益高和可持续性。

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