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基于界面设计工程的钢纤维与热熔胶的界面粘结性能及机理

Interface Bonding Properties and Mechanism of Steel Fiber and Hot Melt Adhesive via Interface Design Engineering.

作者信息

Zhang Tiancan, Liu Shengkai, Zhang Xiaole, Pei Xiaoyuan, Wu Xianyan, Luo Shigang, Xu Wen, Xu Zhiwei

机构信息

Key Laboratory of Advanced Braided Composites, Ministry of Education, School of Textile Science and Engineering, Tiangong University, Tianjin, China 300387.

Carbon Technology Group Co., Ltd., Tianjin, China 300380.

出版信息

Langmuir. 2024 Jan 30;40(4):2301-2310. doi: 10.1021/acs.langmuir.3c03416. Epub 2024 Jan 18.

Abstract

Steel fiber textile, which is composed of steel fibers and glass fibers, has a support layer impregnated with hot melt adhesive (HMA). During long-term service, the bonding force between the steel fiber/HMA system interfaces is poor. In order to improve the bond strength and durability of the interface, this paper introduced sandblasting, acid-etching, and phosphating treatments on the surface of the steel fibers. Also, the effects of these three pretreatment methods on the bond strength of the steel fiber/HMA interface were investigated. The results indicate that the interfacial bond strength of composites made from steel fibers is improved via surface treatment. Under a hydrothermal and simulated concrete pore solution environment, the durability of the steel fiber/HMA interface after sandblasting and acid-etching pretreatment is not as good as that after phosphating pretreatment. The mechanical properties of the phosphating/HMA composite were maintained at 4.56 and 2.24 times compared to those of the untreated/HMA composite, respectively. This is because the pinning effect formed by the phosphating film on the surface of steel fibers at the interface of steel fiber/HMA can serve as a physical barrier against corrosion, preventing the invasion of chloride ions and water vapor and improving the durability of the interface.

摘要

由钢纤维和玻璃纤维组成的钢纤维织物有一个浸渍了热熔胶(HMA)的支撑层。在长期使用过程中,钢纤维/HMA系统界面之间的粘合力较差。为了提高界面的粘结强度和耐久性,本文对钢纤维表面进行了喷砂、酸蚀和磷化处理。此外,还研究了这三种预处理方法对钢纤维/HMA界面粘结强度的影响。结果表明,通过表面处理可提高钢纤维制成的复合材料的界面粘结强度。在水热和模拟混凝土孔隙溶液环境下,喷砂和酸蚀预处理后的钢纤维/HMA界面耐久性不如磷化预处理后的。磷化/HMA复合材料的力学性能分别是未处理/HMA复合材料的4.56倍和2.24倍。这是因为在钢纤维/HMA界面处钢纤维表面的磷化膜形成的钉扎效应可作为一种防腐蚀的物理屏障,防止氯离子和水蒸气的侵入,提高界面的耐久性。

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