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聚甲醛二醇醚聚合物提高原油采收率的性能机理研究

Study on the Performance Mechanism of Polyformaldehyde Glycol Ether Polymer for Crude Oil Recovery Enhancement.

作者信息

Jiang Shaohui, Lu Wenxue, Li Tao, Ma Fujun, Yao Dahu, Li Qingsong

机构信息

The State Key Laboratory of Heavy Oil Processing, China University of Petroleum East China, Qingdao 266580, China.

Shandong Energy Group Co., Ltd., Jinan 250100, China.

出版信息

Materials (Basel). 2024 Jan 16;17(2):437. doi: 10.3390/ma17020437.

Abstract

The demand for energy continues to increase as the global economy continues to grow. The role of oilfield chemicals in the process of oil and gas exploration, development, and production is becoming more and more important, and the demand is rising year by year. The support of national policies and the formulation of environmental protection regulations have put forward higher requirements for oilfield chemical products, which has promoted the innovative research and development and market application of oilfield chemicals. Polyformaldehyde glycol ether polymer (PGEP) is simple to synthesize, easily biodegradable, green and environmentally friendly, and in line with the development trend of chemicals used in oil and gas development. The interfacial tension performance of PGEP after compounding with different surfactants can reach as low as 0.00034 mN/m, which meets the requirements of the oilfield (interfacial tension ≤ 5 × 10 mN/m). The best oil washing efficiency performance of PGEP compounded with different surfactants reached 78.2%, which meets the requirements of the oilfield (oil washing efficiency ≥ 40%). The fracturing fluid drainage efficiency of PGEP after compounding with different surfactants reaches 22%, which meets the requirements of the oilfield (drainage efficiency ≥ 15%). The surface interfacial tension of the system remains constant after the concentration exceeds 0.2% and decreases with lower concentrations. The drainage efficiency increases with increasing concentrations in the range below 0.6%. It was determined that PGEP can be used as a surfactant instead of fatty-alcohol ethoxylates (FAE) in oilfield development.

摘要

随着全球经济持续增长,能源需求不断增加。油田化学品在油气勘探、开发和生产过程中的作用日益重要,需求逐年上升。国家政策的支持和环境保护法规的制定对油田化学产品提出了更高要求,推动了油田化学品的创新研发和市场应用。聚甲醛二醇醚聚合物(PGEP)合成简单,易于生物降解,绿色环保,符合油气开发用化学品的发展趋势。PGEP与不同表面活性剂复配后的界面张力性能可低至0.00034 mN/m,满足油田要求(界面张力≤5×10 mN/m)。PGEP与不同表面活性剂复配后的最佳洗油效率性能达到78.2%,满足油田要求(洗油效率≥40%)。PGEP与不同表面活性剂复配后的压裂液排液效率达到22%,满足油田要求(排液效率≥15%)。体系浓度超过0.2%后表面界面张力保持恒定,较低浓度时则降低。在0.6%以下的浓度范围内,排液效率随浓度增加而提高。经测定,PGEP在油田开发中可替代脂肪醇聚氧乙烯醚(FAE)用作表面活性剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/67a6/10817623/60fa5e87a204/materials-17-00437-g001.jpg

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