Suppr超能文献

用环境友好型表面活性剂烷基多苷冲洗受田间风化原油污染的土壤。

Washing of field weathered crude oil contaminated soil with an environmentally compatible surfactant, alkyl polyglucoside.

作者信息

Han Mei, Ji Guodong, Ni Jinren

机构信息

Department of Environmental Engineering, Peking University, Beijing 100871, China.

出版信息

Chemosphere. 2009 Jul;76(5):579-86. doi: 10.1016/j.chemosphere.2009.05.003. Epub 2009 Jun 2.

Abstract

Weathered crude oil contaminated soils (COCSs), which are much more difficult to remediate than those freshly contaminated, are widespread especially at the sites of oil fields and industries. Surfactant enhanced ex situ soil washing could be used to remediate COCSs, but surfactant toxicity becomes one of the major concerns. In this study, a class of green surfactants, alkyl polyglucosides (APGs), were tested in washing the field weathered COCS with relatively high oil concentration (123 mgg(-1) dry soil) from Jilin Oilfield, Northeastern China. APG1214, characterized with longer alkyl chain, was more effective than APG0810 in crude oil removal. Adding inorganic sodium salts into APG1214 solution further improved the crude oil removal efficiency (CORE). Washing parameters (temperature, washing time, agitation speed and solution/soil ratio) were investigated and further optimized integratedly with an orthogonal design. At the optimum conditions, the CORE reached 97%. GC/MS analysis showed that the proportion of small n-alkanes (C(16)-C(23)) in residual crude oil gradually increased, which was helpful to interpret the oil removal mechanism. Moreover, eminent effect on removal of large n-alkanes was achieved from the synergy between APG1214 and inorganic salts, which was opposite to the effect when they were added separately. This study demonstrated a promising way to remediate COCS with ecologically compatible surfactant and provided guidelines for its practical application.

摘要

风化原油污染土壤(COCSs)比新污染的土壤更难修复,在油田和工业场地广泛存在。表面活性剂强化异位土壤淋洗可用于修复COCSs,但表面活性剂毒性成为主要问题之一。本研究中,一类绿色表面活性剂烷基多苷(APGs)被用于淋洗来自中国东北吉林油田含油浓度相对较高(123 mg g(-1)干土)的现场风化COCSs。具有较长烷基链的APG1214在原油去除方面比APG0810更有效。向APG1214溶液中添加无机钠盐进一步提高了原油去除效率(CORE)。研究了淋洗参数(温度、淋洗时间、搅拌速度和溶液/土壤比),并通过正交设计进行了进一步综合优化。在最佳条件下,CORE达到了97%。气相色谱/质谱分析表明,残留原油中小正构烷烃(C(16)-C(23))的比例逐渐增加,这有助于解释原油去除机制。此外,APG1214与无机盐之间的协同作用对大正构烷烃的去除效果显著,这与它们单独添加时的效果相反。本研究展示了一种用生态兼容表面活性剂修复COCSs的有前景的方法,并为其实际应用提供了指导。

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验