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灰树花多糖:凝胶形成特性及其与食品增稠剂的复合效应。

Polysaccharide from Clitocybe squamulosa: Gel-forming properties and its compound effect with food thickener.

机构信息

College of Food Science and Engineering, Shanxi Agricultural University, Taigu 030801, Shanxi, China; Shanxi Key Laboratory of Edible Fungi for Loess Plateau, Taigu 030801, Shanxi, China.

College of Food Science and Engineering, Shanxi Agricultural University, Taigu 030801, Shanxi, China.

出版信息

Int J Biol Macromol. 2024 Mar;260(Pt 1):129474. doi: 10.1016/j.ijbiomac.2024.129474. Epub 2024 Jan 22.

Abstract

To study the gel-forming properties of polysaccharide from the fruiting body of Clitocybe squamulosa (CSFP) and its degradation product (UH-CSFP), the changes in steady-state and dynamic rheological properties of CSFP and UH-CSFP under different conditions (polysaccharide mass fraction, temperature, pH, and salt ion concentration) were studied. Polysaccharides with good gel-forming properties were selected and mixed with common edible thickeners (gelatin, guar gum, and locust bean gum), after which the properties of the composite gel were assessed. The steady-state rheological results showed that CSFP and UH-CSFP were pseudoplastic fluids, their apparent viscosity decreased with increasing temperature, the viscosity was greatest when the pH was 7. The addition of Na and Ca could increase the viscosity, and the viscosity of UH-CSFP was lower than that of CSFP at the same mass fraction. The results of dynamic rheology indicated that G´ and G´´ of CSFP and UH-CSFP increased with increasing mass fraction, pH, and ion concentration (0.01 M to 1 M), and G´´ was always smaller than G´ indicating weak gel behavior. The thixotropy-related experimental results showed that the thixotropy ring area of CSFP and UH-CSFP increased with increasing mass fraction, the ring area of CSFP was larger than that of UH-CSFP, and the gel strength of CSFP was greater than that of UH-CSFP. The results of CSFP and three types of edible gels showed that the composite gels were pseudoplastic fluids, and their apparent viscosity was ranked (in descending order) as follows: guar bean gum, locust bean gum, and gelatin. The addition of CSFP improved the gel-forming properties of guar gum but did not significantly improve the gel properties of locust bean gum and gelatin. This study provides a theoretical basis for the selection of processing methods and the application of polysaccharides.

摘要

为研究灰树花子实体多糖(CSFP)及其降解产物(UH-CSFP)的凝胶形成特性,研究了不同条件(多糖质量分数、温度、pH 值和盐离子浓度)下 CSFP 和 UH-CSFP 的稳态和动态流变特性的变化。选择具有良好凝胶形成特性的多糖,并与常见的食用增稠剂(明胶、瓜尔胶和槐豆胶)混合,然后评估复合凝胶的性质。稳态流变结果表明,CSFP 和 UH-CSFP 均为假塑性流体,其表观黏度随温度升高而降低,pH 值为 7 时黏度最大。添加 Na 和 Ca 可以增加黏度,且在相同质量分数下,UH-CSFP 的黏度低于 CSFP。动态流变学结果表明,CSFP 和 UH-CSFP 的 G´和 G´´随质量分数、pH 值和离子浓度(0.01~1 M)的增加而增加,且 G´´始终小于 G´,表明为弱凝胶行为。触变性相关实验结果表明,CSFP 和 UH-CSFP 的触变性环面积随质量分数的增加而增加,CSFP 的环面积大于 UH-CSFP,CSFP 的凝胶强度大于 UH-CSFP。CSFP 与三种类型的食用凝胶的结果表明,复合凝胶为假塑性流体,其表观黏度的排序(降序)如下:瓜尔胶、槐豆胶和明胶。CSFP 的添加改善了瓜尔胶的凝胶形成特性,但对槐豆胶和明胶的凝胶性质没有显著改善。本研究为多糖加工方法的选择和应用提供了理论依据。

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