Department of Biotechnology, St. Joseph's College of Engineering, Chennai 600119, India.
Department of Biotechnology, St. Joseph's College of Engineering, Chennai 600119, India.
Bioresour Technol. 2024 Mar;395:130351. doi: 10.1016/j.biortech.2024.130351. Epub 2024 Jan 23.
The present research explored the sustainable production of biodiesel from mixed oils of marine macroalgae and non-edible seeds using a sulphonated Zinc doped recyclable biochar catalyst derived from coconut husk. The maximum biodiesel conversion of 94.8 % was yielded with optimized conditions of 10:1 methanol to oil molar ratio, 4.8 % biochar catalyst concentration, 54.5 ℃ temperature and 87.4 min reaction time. A techno-economic assessment provided a favourable return on investment (ROI) of 21.59 % and 4.63 years of reimbursement period, with a calculated minimum selling price of 0.81 $/kg of produced biodiesel. The carbon footprint analysis results estimated an annual emission of 752.07 t CO which corresponds to 0.088 kg CO emission per kg of biodiesel produced from the simulated process. The study on economic viability and environmental consciousness of biodiesel production not only paves the way for a greener and sustainable future while also contributing to low carbon footprint.
本研究探索了使用源自椰子壳的磺化锌掺杂可回收生物炭催化剂,从海洋大型藻类和非食用种子的混合油中可持续生产生物柴油。在甲醇与油摩尔比为 10:1、生物炭催化剂浓度为 4.8%、温度为 54.5℃和反应时间为 87.4 min 的优化条件下,可获得 94.8%的最大生物柴油转化率。技术经济评估提供了 21.59%的投资回报率和 4.63 年的投资回收期,生产的生物柴油的最低销售价格为 0.81 美元/公斤。碳足迹分析结果估计每年排放 752.07 t CO,相当于模拟过程中每生产 1 kg 生物柴油排放 0.088 kg CO。对生物柴油生产的经济可行性和环境意识的研究不仅为更绿色和可持续的未来铺平了道路,同时也有助于减少碳足迹。