Parzyck C T, Gupta N K, Wu Y, Anil V, Bhatt L, Bouliane M, Gong R, Gregory B Z, Luo A, Sutarto R, He F, Chuang Y-D, Zhou T, Herranz G, Kourkoutis L F, Singer A, Schlom D G, Hawthorn D G, Shen K M
Laboratory of Atomic and Solid State Physics, Department of Physics, Cornell University, Ithaca, NY, USA.
Department of Physics and Astronomy, University of Waterloo, Waterloo, Ontario, Canada.
Nat Mater. 2024 Apr;23(4):486-491. doi: 10.1038/s41563-024-01797-0. Epub 2024 Jan 26.
A hallmark of many unconventional superconductors is the presence of many-body interactions that give rise to broken-symmetry states intertwined with superconductivity. Recent resonant soft X-ray scattering experiments report commensurate 3a charge density wave order in infinite-layer nickelates, which has important implications regarding the universal interplay between charge order and superconductivity in both cuprates and nickelates. Here we present X-ray scattering and spectroscopy measurements on a series of NdNiO samples, which reveal that the signatures of charge density wave order are absent in fully reduced, single-phase NdNiO. The 3a superlattice peak instead originates from a partially reduced impurity phase where excess apical oxygens form ordered rows with three-unit-cell periodicity. The absence of any observable charge density wave order in NdNiO highlights a crucial difference between the phase diagrams of cuprate and nickelate superconductors.
许多非常规超导体的一个标志是存在多体相互作用,这种相互作用会产生与超导性相互交织的破缺对称态。最近的共振软X射线散射实验报告了无限层镍酸盐中存在相称的3a电荷密度波序,这对于铜酸盐和镍酸盐中电荷序与超导性之间的普遍相互作用具有重要意义。在此,我们展示了对一系列NdNiO样品的X射线散射和光谱测量,结果表明在完全还原的单相NdNiO中不存在电荷密度波序的特征。相反,3a超晶格峰源自部分还原的杂质相,其中过量的顶氧形成具有三个晶胞周期的有序行。NdNiO中不存在任何可观测到的电荷密度波序,这突出了铜酸盐和镍酸盐超导体相图之间的一个关键差异。