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规模扩大试验中水泥窑协同焚烧污水污泥生物干化产物的环境影响。

Environmental impacts of cement kiln co-incineration sewage sludge biodried products in a scale-up trial.

机构信息

Center for Environmental Remediation, Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing 100101, China; School of Environment, Tsinghua University, Beijing 100084, China.

College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100049, China; Beijing Greentech Technology Group Co.Ltd., Beijing 100080, China.

出版信息

Waste Manag. 2024 Apr 1;177:24-33. doi: 10.1016/j.wasman.2024.01.043. Epub 2024 Jan 29.

Abstract

The biodrying technology as a pretreatment technology can overcome the limitations of cement kilns co-incineration sewage sludge (SS) on energy consumption. But the impact of SS biodried products on cement kilns and the route carbon reduction potential of biodrying + cement kilns have not been studied. In this study, SS biodrying and cement kiln co-incineration biodried product trials were conducted to highlight the matrix combustion characteristics, and the impact of biodried products on cement kilns (clinker capacity, coal consumption, and pollutant discharge). The carbon emissions of the four scenarios were assessed based on these results. The results showed that water removal rate reached 65.5 % after 11-day biodrying, and the wet-based lower heating value of the biodried product increased by 76.0 % compared with the initial matrix. Comprehensive combustibility index of the biodried product (0.745 × 10 %℃min) was better than that of SS (0.433 × 10 %℃min) although a portion of the organic matter was degraded. Cement kiln co-incineration of biodried products (150 t/d) resulted in per tonne of clinker saved 5.61 kg of coal due to the heat utilization efficiency of biodried products reached to 93.7 %. However, it led to an increase in the emission concentrations of NO and SO. Assessment results indicated that the biodrying + cement kiln pathway reduced CO emissions by 385.7 kg/t SS. Biodried products have greater potential to reduce emissions as alternative fuels than as fertilizers. This study indicated the advantages of SS biodrying + cement kiln co-incineration route.

摘要

生物干化技术作为一种预处理技术,可以克服水泥窑协同焚烧污水污泥(SS)在能耗方面的局限性。但是,SS 生物干化产品对水泥窑的影响以及生物干化+水泥窑的碳减排途径潜力尚未得到研究。在这项研究中,进行了 SS 生物干化和水泥窑协同焚烧生物干化产品试验,以突出基质燃烧特性,以及生物干化产品对水泥窑(熟料产能、煤耗和污染物排放)的影响。根据这些结果评估了四个情景的碳排放。结果表明,经过 11 天的生物干化,水去除率达到 65.5%,生物干化产品的湿基低位热值比初始基质增加了 76.0%。尽管一部分有机物降解,但生物干化产品的综合可燃性指数(0.745×10%℃min)优于 SS(0.433×10%℃min)。由于生物干化产品的热利用效率达到 93.7%,生物干化产品的水泥窑协同焚烧(150 吨/天)导致每吨熟料节省了 5.61 千克煤。然而,这导致了 NO 和 SO 的排放浓度增加。评估结果表明,生物干化+水泥窑途径使每吨 SS 的 CO 排放量减少了 385.7 千克。与作为肥料相比,生物干化产品作为替代燃料具有更大的减排潜力。本研究表明了 SS 生物干化+水泥窑协同焚烧路线的优势。

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