Valiyev Isa, Paul Indrajit, Li Yi-Fan, Elramadi Emad, Schmittel Michael
Center of Micro and Nanochemistry and (Bio)Technology, Organische Chemie I, School of Science and Engineering, Universität Siegen, Adolf-Reichwein-Str. 2, D-57068 Siegen, Germany.
Dalton Trans. 2024 Feb 20;53(8):3454-3458. doi: 10.1039/d3dt04300b.
When the slider-on-deck [Cu(1)(2)] and guest G were treated with palladium(II) ions, the biped 2 was released from [Cu(1)(2)] generating the nanocage [Pd(2)(G)] with guest G being encapsulated (NetState-II). This transformation that was reversed by the addition of DMAP enabled modulation of both the overall fluorescence and the activity of copper(I) catalyzing an aza Hopf cyclization.
当将甲板上的滑块[Cu(1)(2)]和客体G用钯(II)离子处理时，双足体2从[Cu(1)(2)]中释放出来，生成包封有客体G的纳米笼[Pd(2)(G)]（净态-II）。通过加入4-二甲氨基吡啶使这种转变逆转，这能够调节整体荧光以及催化氮杂霍夫环化反应的铜(I)的活性。
