Ghosh Amit, Paul Indrajit, Saha Suchismita, Paululat Thomas, Schmittel Michael
Center of Micro- and Nanochemistry and Engineering , University of Siegen, Organische Chemie I , Adolf-Reichwein-Str. 2 , D-57068 Siegen , Germany.
University of Siegen, Organische Chemie II , Adolf-Reichwein-Str. 2 , D-57068 Siegen , Germany.
Org Lett. 2018 Dec 21;20(24):7973-7976. doi: 10.1021/acs.orglett.8b03541. Epub 2018 Dec 11.
Three-component nanorotor R1 ( k = 80 kHz) and two-component slider-on-deck DS2 ( k = 440 kHz) were prepared from rotator S1 and stator [Cu(1)] and from S2 and deck D, respectively. Mixing of R1 with DS2 leads to clean metathesis, furnishing the slower nanodevices R2 ( k = 29.6 kHz) and DS1 ( k = 32.2 kHz). Exchange of the piston rods S1 and S2 is completed within 22 min (uncatalyzed) or 3 min (catalyzed) at 298 K.
三元纳米转子R1（k = 80千赫兹）和二元甲板上滑块DS2（k = 440千赫兹）分别由转子S1和定子[Cu(1)]以及S2和甲板D制备而成。R1与DS2混合会发生完全复分解反应，生成较慢的纳米器件R2（k = 29.6千赫兹）和DS1（k = 32.2千赫兹）。在298 K下，活塞杆S1和S2的交换在22分钟（无催化）或3分钟（有催化）内完成。
