Singh Ovender, Mok Jungwi, Park Hyoung-Ryun, Lee Junseong
Department of Chemistry, Chonnam National University, Gwangju, Republic of Korea.
IUCrdata. 2024 Jan 26;9(Pt 1):x240059. doi: 10.1107/S2414314624000592. eCollection 2024 Jan.
A new square-planar palladium complex salt hydrate, (CHNO)[PdCl]·0.5HO, has been characterized. The asymmetric unit of the complex salt comprises two [PdCl] dianions, four 2-hy-droxy-2,3-di-hydro-1-inden-1-aminium cations, each derived from (1,2)-(+)-1-amino-indan-2-ol, and one water mol-ecule of crystallization. In the crystal, a two-dimensional layer parallel to (001) features a number of O-H⋯O, N-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonds.
一种新型的平面正方形钯配合物盐水合物(CHNO)[PdCl]·0.5HO已被表征。该配合物盐的不对称单元包括两个[PdCl]二价阴离子、四个2-羟基-2,3-二氢-1-茚-1-铵阳离子(每个阳离子均衍生自(1,2)-(+)-1-氨基茚满-2-醇)和一个结晶水分子。在晶体中,平行于(001)的二维层具有许多O-H⋯O、N-H⋯O、O-H⋯Cl和N-H⋯Cl氢键。