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改性聚四氟乙烯高温电绝缘性能研究

Study on the Electrical Insulation Properties of Modified PTFE at High Temperatures.

作者信息

Yuan Lijian, Zheng Xu, Zhu Wenbo, Wang Bin, Chen Yuanyuan, Xing Yunqi

机构信息

School of Electrical and Electronic Engineering, Shandong University of Technology, Zibo 255000, China.

Shandong Dianliangliang Energy Technology Co., Ltd., Jinan 250000, China.

出版信息

Polymers (Basel). 2024 Jan 24;16(3):316. doi: 10.3390/polym16030316.

DOI:10.3390/polym16030316
PMID:38337205
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10857613/
Abstract

During the operation of multi-electric aircraft, the polytetrafluoroethylene (PTFE) material used to insulate the aviation cable is subjected to a high electric field while working under the extreme conditions of high temperatures for a long time, which can easily cause a partial discharge and even flashover along the surface, which seriously threaten the safe operation of the aircraft. In this paper, the electrical insulation properties of PTFE were regulated via modification by the magnetron sputtering of TiO under high temperatures, and modified PTFE with different sputtering times was prepared. The direct current (DC) surface discharge, surface flashover, and electric aging characteristics of modified PTFE were studied under the condition of 20~200 °C, and the mechanisms by which modification by sputtering of TiO and high temperature influence the insulation properties were analyzed. The results show that the surface discharge intensity increases with the increase in temperature, the modification by sputtering of TiO can significantly inhibit the partial discharge of PTFE, and the flashover voltage first increases and then decreases with the increase in the modification time. The modification by magnetron sputtering can effectively increase the surface potential decay rate of the PTFE, increase the shallow trap energy density, effectively avoid charge accumulation, inhibit the partial discharge phenomenon, and improve the surface electrical insulation and anti-aging properties.

摘要

在多电飞机运行过程中,用于航空电缆绝缘的聚四氟乙烯(PTFE)材料在长时间高温的极端条件下工作时会受到高电场作用,这容易导致局部放电甚至沿表面闪络,严重威胁飞机的安全运行。本文通过高温下TiO的磁控溅射改性来调控PTFE的电绝缘性能,制备了不同溅射时间的改性PTFE。研究了改性PTFE在20~200℃条件下的直流(DC)表面放电、表面闪络和电老化特性,并分析了TiO溅射改性和高温影响绝缘性能的机理。结果表明,表面放电强度随温度升高而增大,TiO溅射改性可显著抑制PTFE的局部放电,闪络电压随改性时间增加先增大后减小。磁控溅射改性可有效提高PTFE的表面电位衰减率,增加浅陷阱能量密度,有效避免电荷积累,抑制局部放电现象,提高表面电绝缘和抗老化性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f5f/10857613/a164c4c0c4a1/polymers-16-00316-g015.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f5f/10857613/d55795f23c69/polymers-16-00316-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f5f/10857613/727efda8173c/polymers-16-00316-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f5f/10857613/4b1b28c77b49/polymers-16-00316-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f5f/10857613/784f4a018da1/polymers-16-00316-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f5f/10857613/ecdab86ef49d/polymers-16-00316-g011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f5f/10857613/a164c4c0c4a1/polymers-16-00316-g015.jpg

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本文引用的文献

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BaSO/TiO Microparticle Embedded in Polyvinylidene Fluoride-Co-Hexafluoropropylene/Polytetrafluoroethylene Polymer Film for Daytime Radiative Cooling.嵌入聚偏氟乙烯 - 共 - 六氟丙烯/聚四氟乙烯聚合物薄膜用于日间辐射冷却的硫酸钡/二氧化钛微粒
Polymers (Basel). 2023 Sep 25;15(19):3876. doi: 10.3390/polym15193876.
2
Rapid Transformation in Wetting Properties of PTFE Membrane Using Plasma Treatment.利用等离子体处理实现聚四氟乙烯膜润湿性能的快速转变
Polymers (Basel). 2023 Sep 24;15(19):3874. doi: 10.3390/polym15193874.
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The Study Influence Analysis of the Mathematical Model Choice for Describing Polymer Behavior.
描述聚合物行为的数学模型选择的研究影响分析
Polymers (Basel). 2023 Sep 1;15(17):3630. doi: 10.3390/polym15173630.
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Effect of CuO and Graphene on PTFE Microfibers: Experimental and Modeling Approaches.氧化铜和石墨烯对聚四氟乙烯微纤维的影响:实验与建模方法
Polymers (Basel). 2022 Mar 8;14(6):1069. doi: 10.3390/polym14061069.