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氧化石墨烯掺杂环氧树脂-氮化镧复合绝缘材料的表面放电特性研究

Study on Surface Discharge Characteristics of GO-Doped Epoxy Resin-LN Composite Insulation.

作者信息

Xing Yunqi, Chen Yuanyuan, Yuan Ruiyi, Yang Zhuoran, Yao Tianyi, Li Jiehua, Zhu Wenbo, Wang Xiaoxue

机构信息

State Key Laboratory of Reliability and Intelligence of Electrical Equipment, Hebei University of Technology, Tianjin 300401, China.

Key Laboratory of Electromagnetic Field and Electrical Apparatus Reliability of Hebei Province, Hebei University of Technology, Tianjin 300401, China.

出版信息

Polymers (Basel). 2022 Mar 31;14(7):1432. doi: 10.3390/polym14071432.

Abstract

Superconducting power lead equipment for epoxy insulation, such as high-temperature superconducting DC power or liquefied natural gas energy pipelines, as well as high-temperature superconducting cables, has long been used in extreme environments, from liquid nitrogen temperatures to normal temperatures. It is easy to induce surface discharge and flashover under the action of strong electric field, which accelerates the insulation failure of current leads. In this paper, two-dimensional nano-material GO was used to control the electrical properties of epoxy resins. The DC surface discharge and flashover characteristics of the prepared epoxy resin-GO composite insulation materials were tested at room temperature with liquid nitrogen. The surface discharge mechanism of the epoxy resin-GO composite insulation materials was analyzed. The experimental results show that the insulation properties of epoxy composites doped with GO changed. Among them, the surface flashover voltage of 0.05 wt% material is the best, which can inhibit the discharge phenomenon and improve its insulation properties in extreme environments, from room temperature to liquid nitrogen temperature. It is found that the development process of surface discharge of composite insulating materials under liquid nitrogen is quite different from that under room temperature. Before critical flashover, the repetition rate and amplitude of surface discharge remain at a low level until critical flashover. Furthermore, the voltage of the first flashover is significantly higher than that of the subsequent flashover under the action of the desorption gas on the surface of the composite insulating material and the gasification layer produced by the discharge. Given that the surface flashover voltage of 0.05 wt% epoxy composite is the best, the research and analysis of 0.05 wt% composite is emphasized. In the future design of superconducting power lead insulation, the modification method of adding GO to epoxy resin can be considered in order to improve its insulation performance.

摘要

用于环氧绝缘的超导电力引线设备,如高温超导直流电力或液化天然气能源管道以及高温超导电缆,长期以来一直在从液氮温度到常温的极端环境中使用。在强电场作用下很容易引发表面放电和闪络,这加速了电流引线的绝缘失效。本文采用二维纳米材料氧化石墨烯(GO)来调控环氧树脂的电学性能。在室温及液氮条件下测试了制备的环氧树脂 - GO复合绝缘材料的直流表面放电和闪络特性。分析了环氧树脂 - GO复合绝缘材料的表面放电机理。实验结果表明,掺杂GO的环氧复合材料的绝缘性能发生了变化。其中,0.05 wt%材料的表面闪络电压最佳,它能抑制放电现象并在从室温到液氮温度的极端环境中提高其绝缘性能。发现复合绝缘材料在液氮下的表面放电发展过程与室温下有很大不同。在临界闪络之前,表面放电的重复率和幅度一直保持在较低水平直至临界闪络。此外,在复合绝缘材料表面的解吸气体和放电产生的气化层作用下,首次闪络的电压明显高于后续闪络的电压。鉴于0.05 wt%环氧复合材料的表面闪络电压最佳,着重对0.05 wt%复合材料进行了研究分析。在未来超导电力引线绝缘设计中,可考虑采用向环氧树脂中添加GO的改性方法来提高其绝缘性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8909/9003141/2fcb26d16f24/polymers-14-01432-g001.jpg

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