Yolk shell structured YS-Si@N-doped carbon derived from covalent organic frameworks for enhanced lithium storage.

Silicon (Si) has ultra-high theoretical capacity (4200 mAh g) and accordingly is widely studied as anode materials for lithium-ion batteries (LIBs). However, its huge volume expansion during charging/discharging is a fatal challenge. The preparation of Si-based composite materials with yolk shell structure is the key to solving the Si volume expansion. Here, N-doped carbon-coated Si nanoparticles (SiNPs) nanocomposites (YS-Si@NC-60) with yolk shell structure derived from covalent organic frameworks (COFs) was prepared. N-doped carbon shells derived from COFs not only maintain the well-ordered nanosized pores of COFs, which facilitates the transport of Li to contact with internal SiNPs, but also provide more extra active sites for Li storage. Most importantly, the internal void can effectively alleviate the damage effect of SiNPs volume expansion. The obtained YS-Si@NC-60 as a LIBs anode show high cyclic stability and Li storage performances. At 0.1 A g, the capacity is 1446 mAh g after 110 cycles, and initial coulomb efficiency is as high as 82.2 %. The excellent performance can be attributed to the unique yolk shell structure. This simple and template-free strategy provides a new idea for preparing Si-C nanocomposites with yolk shell structure.