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由甘蔗渣灰衍生的高锰酸钾浸渍无定形硅铝酸盐作为乙烯清除剂用于延长芒果果实货架期

Potassium Permanganate-Impregnated Amorphous Silica-Alumina Derived from Sugar Cane Bagasse Ash as an Ethylene Scavenger for Extending Shelf Life of Mango Fruits.

作者信息

Chanka Napassorn, Donphai Waleeporn, Chareonpanich Metta, Faungnawakij Kajornsak, Rupprechter Günther, Seubsai Anusorn

机构信息

Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, Thailand.

Center of Excellence on Petrochemical and Materials Technology, Kasetsart University, Bangkok 10900, Thailand.

出版信息

ACS Omega. 2024 Feb 2;9(6):6749-6760. doi: 10.1021/acsomega.3c08119. eCollection 2024 Feb 13.

Abstract

Ethylene, a plant hormone, is a gas that plays a crucial role in fruit ripening and senescence. In this work, a novel ethylene scavenger was prepared from amorphous silica-alumina derived from sugar cane bagasse ash (SC-ASA) and used to prolong the shelf life of mango fruits during storage. KMnO at 2, 4, or 6 wt %/w was loaded on SC-ASA using an impregnation method. The results showed that 4% w/w KMnO loaded on SC-ASA (4KM/SC-ASA) was superior for ethylene removal at an initial ethylene concentration of 400 μL L for 120 min under ambient conditions (25-27 °C and 70-75% relative humidity), resulting in 100% ethylene removal. The kinetic study of ethylene removal showed that the adsorption data were best fitted with a pseudo-first-order kinetic model. The effects of 4KM/SC-ASA as sachets on the quality changes of the mango fruits were investigated, with the results showing that mango fruits packed in cardboard boxes with 4KM/SC-ASA had significantly delayed ripening, low levels of ethylene production, respiration, and weight loss, high fruit firmness, low total soluble solids, and high acidity compared to those of the control treatment. These findings should contribute to developing an ethylene scavenger to extend the shelf life of fruits, reduce the waste of the sugar and ethanol industries, and make it a valuable material.

摘要

乙烯是一种植物激素,是一种在果实成熟和衰老过程中起关键作用的气体。在这项工作中,一种新型乙烯清除剂由甘蔗渣灰衍生的无定形硅铝酸盐制备而成,并用于延长芒果在储存期间的货架期。采用浸渍法将2%、4%或6%重量/重量的高锰酸钾负载在甘蔗渣灰衍生的无定形硅铝酸盐上。结果表明,在环境条件(25 - 27°C和70 - 75%相对湿度)下,初始乙烯浓度为400 μL/L时,负载4%重量/重量高锰酸钾的甘蔗渣灰衍生的无定形硅铝酸盐(4KM/SC - ASA)在120分钟内对乙烯的去除效果最佳,乙烯去除率达100%。乙烯去除的动力学研究表明,吸附数据最符合准一级动力学模型。研究了作为小包装的4KM/SC - ASA对芒果果实品质变化的影响,结果表明,与对照处理相比,用装有4KM/SC - ASA的纸箱包装的芒果果实成熟显著延迟,乙烯产生量、呼吸作用和重量损失较低,果实硬度高,总可溶性固形物含量低,酸度高。这些发现应有助于开发一种乙烯清除剂,以延长水果的货架期,减少制糖和乙醇行业的废弃物,并使其成为一种有价值的材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d292/10870304/f917b5a79b42/ao3c08119_0001.jpg

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