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太阳能激活和水热合成的有效 rGO/AgS 复合材料用于破坏萘酚绿 B 染料和抗菌应用。

Solar-activated and hydrothermally synthesized effective rGO/AgS composites for the destruction of naphthol green B dye and antibacterial applications.

机构信息

Department of Chemistry, Annamalai University, Annamalainagar, Tamil Nadu, 608002, India.

Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences (SIMATS), Chennai, Tamil Nadu, 602105, India.

出版信息

Environ Geochem Health. 2024 Feb 20;46(3):95. doi: 10.1007/s10653-024-01876-w.

Abstract

Graphene-based nanocomposites are developing as a new class of materials with several uses. The varied weight percentages of rGO on AgS catalysts were synthesized using a simple hydrothermal process and employed for the decomposition of anionic dye naphthol green B (NGB) under solar light. The reduced graphene oxide-based silver sulfide (rGO/AgS) nanoparticles were then examined using XRD, SEM, EDS, HR-TEM, XPS, UV-DRS, and PL analysis. Using solar light, the photocatalytic activity of the produced catalyst was examined for the degradation of naphthol green B (NGB) in an aqueous solution. At pH 9, rGO/AgS is discovered to be more effective than the other catalysts for the NGB dye mineralization. Analyses have been conducted on the influence of operational parameters on the photo-mineralization of NGB, including the initial pH, initial dye concentration, and catalyst dosage. The dye concentration increased; the efficiency of photocatalytic degradation tended to decrease. Chemical oxygen demand (COD) studies have verified the NGB dye mineralization. Active species trapping revealed that holes, hydroxyl radicals, and superoxide radicals all played major roles in the photocatalytic deterioration of NGB processes. Additionally, a potential mechanism of NGB dye degradation by rGO/AgS catalyst is presented. The synthesized compound was further evaluated for antibacterial activity, and the results indicated that rGO/AgS were potentially effective antibacterial agents.

摘要

基于石墨烯的纳米复合材料作为一类具有多种用途的新材料正在发展。通过简单的水热法合成了具有不同 rGO 重量百分比的 AgS 催化剂,并将其用于在太阳光下分解阴离子染料萘酚绿 B (NGB)。然后使用 XRD、SEM、EDS、HR-TEM、XPS、UV-DRS 和 PL 分析对基于还原氧化石墨烯的硫化银 (rGO/AgS) 纳米粒子进行了检查。使用太阳光,研究了所制备的催化剂对水溶液中萘酚绿 B (NGB) 的光催化降解活性。在 pH 9 时,rGO/AgS 比其他催化剂更有效地实现 NGB 染料矿化。对操作参数对 NGB 光矿化的影响进行了分析,包括初始 pH 值、初始染料浓度和催化剂用量。随着染料浓度的增加,光催化降解效率趋于降低。化学需氧量 (COD) 研究验证了 NGB 染料矿化。活性物种捕获表明空穴、羟基自由基和超氧自由基都在 NGB 光催化降解过程中起主要作用。此外,还提出了 rGO/AgS 催化剂降解 NGB 染料的潜在机制。进一步评估了合成化合物的抗菌活性,结果表明 rGO/AgS 可能是有效的抗菌剂。

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