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扩大基于粉煤灰的地质聚合物混凝土规模,以研究当地可得偏高岭土与粉煤灰的二元效应。

Up-scaling of fly ash-based geopolymer concrete to investigate the binary effect of locally available metakaolin with fly ash.

作者信息

Ashfaq Muhammad Hassan, Sharif Muhammad Burhan, Irfan-Ul-Hassan Muhammad, Sahar Umbreen Us, Akmal Usman, Mohamed Abdullah

机构信息

Irrigation Department, Government of the Punjab, Library Road, Lahore, Pakistan.

Department of Civil Engineering, University of Engineering and Technology, Lahore, Pakistan.

出版信息

Heliyon. 2024 Feb 14;10(4):e26331. doi: 10.1016/j.heliyon.2024.e26331. eCollection 2024 Feb 29.

DOI:10.1016/j.heliyon.2024.e26331
PMID:38390164
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10882126/
Abstract

Owing to the increasing threat to environment due to the emission of greenhouse gases from cement industry globally, various promising solutions has been introduced in the past decades. The development of geoplymer concrete (GPC) is one of the contribution by the researches towards ecofriendly and sustainable construction. In this research, geopolymer concrete (GPC) is optimized by adding fixed amount of fly Ash (FA) and alkali activator to fine aggregate ratio as 0.5 with varying Molarity from 12 M to 16 M and /NaOH ratio from 1.5 to 2.5. Physical and mechanical properties along with effect of heat and ambient curing conditions were investigated at various ages. The optimized mixture of fly ash based geopolymer concrete was then up scaled by blending with locally available Metakaolin (MK) with different dosages (i.e., 10%, 20%, 30%, 40%). The aim of the study is to identify the binary effect of FA and MK on overall performance of geopolymer concrete. Results showed that 30% FA-MK based GPC depicted 21%, 19% and 26% more compressive strength, split tensile strength and flexural strength respectively than Fly Ash based GPC alone at heat cured condition. This can be explained mainly due to two facts namely binary action of metakaolin that enhances compaction of GPC and pozzolanic activity of MK that expedite geopolymeric strength causing phases. The results were further verified by Modified Chapelle test and FTIR. Morphology of the developed GPC is also examined from SEM images. The work is an effort to utilize the fly ash produced by coal power plants to effectively address UN sustainable development goal related to sustainable cities and communities.

摘要

由于全球水泥行业排放温室气体对环境的威胁日益增加,在过去几十年中已引入了各种有前景的解决方案。地聚合物混凝土(GPC)的开发是研究人员对生态友好型和可持续建筑的贡献之一。在本研究中,通过添加固定量的粉煤灰(FA)和碱激发剂,将细集料比例优化为0.5,摩尔浓度从12M变化到16M,NaOH比例从1.5变化到2.5,对地质聚合物混凝土(GPC)进行优化。研究了不同龄期的物理和力学性能以及热养护和环境养护条件的影响。然后,通过与不同剂量(即10%、20%、30%、- 40%)的当地偏高岭土(MK)混合,扩大了基于粉煤灰的地聚合物混凝土的优化混合物规模。该研究的目的是确定FA和MK对地质聚合物混凝土整体性能的二元效应。结果表明,在热养护条件下,30% FA - MK基GPC的抗压强度、劈裂抗拉强度和抗弯强度分别比单独的粉煤灰基GPC高21%、19%和26%。这主要可以由两个事实来解释,即偏高岭土的二元作用增强了GPC的压实度,以及MK的火山灰活性加速了地质聚合物强度形成相。通过改进的查佩尔试验和傅里叶变换红外光谱(FTIR)进一步验证了结果。还从扫描电子显微镜(SEM)图像检查了所开发GPC的形态。这项工作旨在利用煤电厂产生的粉煤灰,有效实现与可持续城市和社区相关的联合国可持续发展目标。

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