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不同养护制度下堿性激发剂对环保地聚合物混凝土力学性能的影响。

Influence of alkaline activators on mechanical properties of environmentally friendly geopolymer concrete under different curing regimes.

机构信息

Civil Engineering Department, University of Engineering and Technology, Lahore, 54890, Pakistan.

University of Wollongong, Wollongong, Australia.

出版信息

Environ Sci Pollut Res Int. 2024 Oct;31(50):60619-60639. doi: 10.1007/s11356-024-35232-3. Epub 2024 Oct 10.

Abstract

Previous studies highlighted the significance of tailoring alkaline activators (AA) to specific fly ash (FA) sources for optimal properties of geopolymer concrete (GPC). This study examines the influence of various AA's properties on mechanical properties and microstructures of local low-calcium FA-based GPC under varying curing conditions. A comprehensive investigation consists of several factors such as NaOH molarities (10 M, 12 M, 14 M, 16 M), ratios (1.5, 2.0, 2.5) and ratios (0.5, 0.6). The results reveal a complex relationship, demonstrating that NaOH molarity positively influences compressive strength up to a threshold of 14 M, beyond which an adverse effect was observed while, the flexural strength was increased up to 16 M. Moreover, the study highlights the complex relationship between ratios and mechanical strengths. Notably, these properties exhibited an increase as the ratio rose up to 2.0, but a subsequent decrease was observed when the ratio reached 2.5. Moreover, proposed regression equations predict the compressive and flexural strengths of both ambient-cured GPC and heat-cured GPC with marginal statistical errors. The optimal GPC mix exhibited 49% lower embodied emissions than the corresponding OPC concrete. GPC has higher cost, but it exhibited lower cost-to-strength ratio compared to OPC concrete.

摘要

先前的研究强调了针对特定粉煤灰(FA)来源定制碱性激发剂(AA)的重要性,以获得最佳的地质聚合物混凝土(GPC)性能。本研究探讨了在不同养护条件下,不同 AA 特性对本地低钙 FA 基 GPC 力学性能和微观结构的影响。综合研究包括多种因素,如 NaOH 浓度(10 M、12 M、14 M、16 M)、模数(1.5、2.0、2.5)和硅铝比(0.5、0.6)。结果表明存在复杂的关系,表明 NaOH 浓度对抗压强度的影响呈正相关,在达到 14 M 的阈值之前,抗压强度增加,超过此值后,抗压强度会下降;而对弯曲强度的影响则呈正相关,直至达到 16 M。此外,研究还强调了模数比与力学强度之间的复杂关系。值得注意的是,这些特性在模数比上升到 2.0 时呈增加趋势,但当模数比达到 2.5 时则呈下降趋势。此外,提出的回归方程可以预测常温养护和热养护 GPC 的抗压强度和弯曲强度,其统计误差较小。最优 GPC 混合物的隐含碳排放量比相应的 OPC 混凝土低 49%。GPC 的成本较高,但与 OPC 混凝土相比,其成本强度比更低。

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