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硫掺杂 g-C<sub>3</sub>N<sub>4</sub>负载碲化锡纳米粒子的绿色合成:对亚甲基蓝光降解和抗菌性能的研究。

Green synthesis of tellurium-doped SnO nanoparticles with sulfurized g-C N : Insights into methylene blue photodegradation and antibacterial capability.

机构信息

Department of Chemistry, University of Engineering and Technology Lahore, Lahore, Pakistan.

Department of Chemistry, School of Science, University of Management and Technology, Lahore, Pakistan.

出版信息

Luminescence. 2024 Feb;39(2):e4693. doi: 10.1002/bio.4693.

DOI:10.1002/bio.4693
PMID:38403841
Abstract

The construction of SnO nanoparticles (NPs), specifically Te-doped SnO NPs, using a simple and economical co-precipitation technique has been thoroughly described in this work. NH served as the reducing agent in this procedure, whilst polyethylene glycol served as the capping agent. The primary goals of our work were to investigate the physicochemical properties of the synthesized SnO NPs and assess their potential use as antibacterial agents and photocatalysts. Scanning electron microscopy-energy dispersive X-ray, ultraviolet light, Fourier transform infrared spectroscopy, X-ray diffraction (XRD), and other analytical techniques were used to thoroughly analyze the NPs. Based on the full width at half maximum of the most noticeable peaks in the XRD spectrum, the Debye-Scherrer equation was used to calculate the crystallite sizes, which indicated the presence of a single tetragonal SnO phase. Particularly noteworthy was the exceptional photocatalytic activity of graphene-assisted Te-doped SnO NPs, achieving an impressive decomposition efficiency of up to 98% in the photo-oxidation of methylene blue. Furthermore, our investigation delved into the antibacterial attributes of the synthesized SnO NPs against Escherichia coli and Staphylococcus aureus, demonstrating inhibitory effects on both bacteria strains. This suggests potential applications for these NPs in various environmental and medical contexts.

摘要

本文详细描述了使用简单经济的共沉淀技术制备 SnO 纳米颗粒(NPs),特别是 Te 掺杂 SnO NPs 的过程。在该过程中,NH 用作还原剂,而聚乙二醇用作包覆剂。我们工作的主要目的是研究合成的 SnO NPs 的物理化学性质,并评估它们作为抗菌剂和光催化剂的潜在用途。使用扫描电子显微镜-能量色散 X 射线、紫外光、傅里叶变换红外光谱、X 射线衍射(XRD)和其他分析技术对 NPs 进行了全面分析。基于 XRD 光谱中最明显峰的半高全宽,使用德拜-谢勒方程计算了晶粒度,表明存在单一的四方 SnO 相。特别值得注意的是,石墨烯辅助 Te 掺杂 SnO NPs 具有出色的光催化活性,在亚甲基蓝的光氧化中达到了高达 98%的分解效率。此外,我们的研究还深入探讨了合成的 SnO NPs 对大肠杆菌和金黄色葡萄球菌的抗菌特性,表明对这两种细菌株均具有抑制作用。这表明这些 NPs 在各种环境和医疗应用中具有潜在的应用前景。

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