Simenas Mantas, Gagor Anna, Banys Juras, Maczka Miroslaw
Faculty of Physics, Vilnius University, Sauletekio 3, LT-10257 Vilnius, Lithuania.
Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Okólna 2, PL-50-422 Wroclaw, Poland.
Chem Rev. 2024 Mar 13;124(5):2281-2326. doi: 10.1021/acs.chemrev.3c00532. Epub 2024 Feb 29.
Lead halide perovskites are extensively investigated as efficient solution-processable materials for photovoltaic applications. The greatest stability and performance of these compounds are achieved by mixing different ions at all three sites of the APbX structure. Despite the extensive use of mixed lead halide perovskites in photovoltaic devices, a detailed and systematic understanding of the mixing-induced effects on the structural and dynamic aspects of these materials is still lacking. The goal of this review is to summarize the current state of knowledge on mixing effects on the structural phase transitions, crystal symmetry, cation and lattice dynamics, and phase diagrams of three- and low-dimensional lead halide perovskites. This review analyzes different mixing recipes and ingredients providing a comprehensive picture of mixing effects and their relation to the attractive properties of these materials.
卤化铅钙钛矿作为用于光伏应用的高效可溶液加工材料受到广泛研究。通过在APbX结构的所有三个位点混合不同离子,可实现这些化合物的最大稳定性和性能。尽管混合卤化铅钙钛矿在光伏器件中得到广泛应用,但仍缺乏对混合诱导效应在这些材料的结构和动力学方面的详细而系统的理解。本综述的目的是总结关于混合效应在三维和低维卤化铅钙钛矿的结构相变、晶体对称性、阳离子和晶格动力学以及相图方面的当前知识状态。本综述分析了不同的混合配方和成分,全面呈现了混合效应及其与这些材料吸引人的特性之间的关系。