Semenikhin Oleksandr A, Kucheriv Olesia I, Sacarescu Liviu, Shova Sergiu, Gural'skiy Il'ya A
Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64, Kyiv, 01601, Ukraine.
Department of Inorganic Polymers, Petru Poni Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda 41-A, Iasi, 700487, Romania.
Chem Commun (Camb). 2023 Mar 21;59(24):3566-3569. doi: 10.1039/d2cc06791a.
3D hybrid perovskites based upon small organic cations gave start to a new intensively growing class of semiconducting materials. Here we report on the elaboration of quantum dots of a recently emerged new perovskite (AzrH)PbBr (AzrH = aziridinium cation). By employing the antisolvent precipitation technique and stabilization with a cationic surfactant we succeeded in obtaining quantum dots that display tunable luminescence. This piece of work shows the perspective of aziridinium-based materials for the elaboration of advanced photonic nanostructures.
基于小有机阳离子的3D混合钙钛矿开启了一类新的快速发展的半导体材料。在此,我们报告了一种新出现的钙钛矿(AzrH)PbBr(AzrH = 氮丙啶鎓阳离子)量子点的制备。通过采用反溶剂沉淀技术并用阳离子表面活性剂进行稳定化处理,我们成功获得了具有可调谐发光特性的量子点。这项工作展示了基于氮丙啶鎓的材料在制备先进光子纳米结构方面的前景。