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通过负载银来提高 WO 薄膜在室温下对氢气传感器的响应。

Enhanced response of WO thin film through Ag loading towards room temperature hydrogen gas sensor.

机构信息

Department of Physics, Indian Institute of Information Technology, Design and Manufacturing, Kancheepuram, Off Vandalur-Kelambakkam Road, Chennai, 600127, India.

Division of Physics, School of Advanced Sciences, Vellore Institute of Technology (VIT), Vandalur-Kelambakkam Road, Chennai, 600127, India.

出版信息

Chemosphere. 2024 Apr;353:141545. doi: 10.1016/j.chemosphere.2024.141545. Epub 2024 Feb 29.

Abstract

This study investigates the enhancement of hydrogen gas-sensing performance by introducing silver (Ag) nanoparticles onto tungsten trioxide (WO) thin films. Herein, the WO thin films are deposited onto SiO/Si substrates using a sputtering technique and Ag nanoparticles are loaded onto the WO surface through a spin coating technique. To evaluate the sensing performance of a hydrogen gas, interdigitated titanium (Ti) electrodes are deposited onto the Ag:WO layer. Structural, chemical, and morphological analyses are conducted for both pristine WO and Ag:WO thin films, followed by the investigation of gas-sensing performance by varying hydrogen gas concentrations from 100 ppm to 300 ppm and operating temperatures between 30 °C and 300 °C. The obtained results demonstrate that Ag:WO thin films exhibit a notably enhanced response of 5.08% when exposed to a concentration of 100 ppm of hydrogen gas at room temperature, compared to the pristine WO of 3.40%. The fabricated Ag:WO sensor exhibits a response time of 3.0 s, a recovery time of 4.5 s, and also demonstrates excellent stability over 45 days period. Finally, with the superior sensitivity and fast response time, the fabricated Ti/Ag:WO/Ti hydrogen gas sensor test-device can be a potential for improvement of safety from both industrial and environmental perspectives.

摘要

本研究通过在三氧化钨 (WO) 薄膜上引入银 (Ag) 纳米粒子来提高氢气传感性能。在此,通过溅射技术将 WO 薄膜沉积在 SiO2/Si 衬底上,并通过旋涂技术将 Ag 纳米粒子负载到 WO 表面。为了评估氢气的传感性能,将叉指钛 (Ti) 电极沉积在 Ag:WO 层上。对原始 WO 和 Ag:WO 薄膜进行了结构、化学和形态分析,然后通过在 30°C 至 300°C 的温度范围内改变氢气浓度从 100 ppm 到 300 ppm 来研究气体传感性能。结果表明,与原始 WO 的 3.40%相比,当暴露于室温下浓度为 100 ppm 的氢气时,Ag:WO 薄膜的响应提高到 5.08%。所制备的 Ag:WO 传感器的响应时间为 3.0s,恢复时间为 4.5s,并且在 45 天的时间内也表现出出色的稳定性。最后,由于具有优异的灵敏度和快速的响应时间,所制备的 Ti/Ag:WO/Ti 氢气气体传感器测试装置有望从工业和环境两个方面提高安全性。

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