Department of Physics, Indian Institute of Information Technology, Design and Manufacturing, Kancheepuram, Off Vandalur-Kelambakkam Road, Chennai, 600127, India.
Division of Physics, School of Advanced Sciences, Vellore Institute of Technology (VIT), Vandalur-Kelambakkam Road, Chennai, 600127, India.
Chemosphere. 2024 Apr;353:141545. doi: 10.1016/j.chemosphere.2024.141545. Epub 2024 Feb 29.
This study investigates the enhancement of hydrogen gas-sensing performance by introducing silver (Ag) nanoparticles onto tungsten trioxide (WO) thin films. Herein, the WO thin films are deposited onto SiO/Si substrates using a sputtering technique and Ag nanoparticles are loaded onto the WO surface through a spin coating technique. To evaluate the sensing performance of a hydrogen gas, interdigitated titanium (Ti) electrodes are deposited onto the Ag:WO layer. Structural, chemical, and morphological analyses are conducted for both pristine WO and Ag:WO thin films, followed by the investigation of gas-sensing performance by varying hydrogen gas concentrations from 100 ppm to 300 ppm and operating temperatures between 30 °C and 300 °C. The obtained results demonstrate that Ag:WO thin films exhibit a notably enhanced response of 5.08% when exposed to a concentration of 100 ppm of hydrogen gas at room temperature, compared to the pristine WO of 3.40%. The fabricated Ag:WO sensor exhibits a response time of 3.0 s, a recovery time of 4.5 s, and also demonstrates excellent stability over 45 days period. Finally, with the superior sensitivity and fast response time, the fabricated Ti/Ag:WO/Ti hydrogen gas sensor test-device can be a potential for improvement of safety from both industrial and environmental perspectives.
本研究通过在三氧化钨 (WO) 薄膜上引入银 (Ag) 纳米粒子来提高氢气传感性能。在此,通过溅射技术将 WO 薄膜沉积在 SiO2/Si 衬底上,并通过旋涂技术将 Ag 纳米粒子负载到 WO 表面。为了评估氢气的传感性能,将叉指钛 (Ti) 电极沉积在 Ag:WO 层上。对原始 WO 和 Ag:WO 薄膜进行了结构、化学和形态分析,然后通过在 30°C 至 300°C 的温度范围内改变氢气浓度从 100 ppm 到 300 ppm 来研究气体传感性能。结果表明,与原始 WO 的 3.40%相比,当暴露于室温下浓度为 100 ppm 的氢气时,Ag:WO 薄膜的响应提高到 5.08%。所制备的 Ag:WO 传感器的响应时间为 3.0s,恢复时间为 4.5s,并且在 45 天的时间内也表现出出色的稳定性。最后,由于具有优异的灵敏度和快速的响应时间,所制备的 Ti/Ag:WO/Ti 氢气气体传感器测试装置有望从工业和环境两个方面提高安全性。